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- W2320034086 abstract "Abstract Treatment of [{(C 6 F 5 )(PPh 3 )Pt(μ-PPh 2 )(μ-H)} 2 Pt] ( 1 ) with I 2 results in a complicated reaction from which [{(C 6 F 5 )(PPh 3 )Pt(μ-PPh 2 )(μ-I)} 2 Pt] ( 2 ) is obtained. The X-ray structure and 19 F and 31 P NMR spectra are given. Density functional theory (DFT) at the B3LYP level, using the LANL2DZ basis set, provides a satisfactory description of structural, bonding, electronic and related properties of [{(CF 3 )(PH 3 )Pt(μ-PH 2 )(μ-H)} 2 Pt] and [{(CF 3 )(PH 3 )Pt(μ-PH 2 )(μ-I)} 2 Pt] model compounds. The results unambiguously justify the predictions of the through-ring bonding required by the number of framework electrons and threw light on the bonding mechanism in the “{Pt(μ-X)(μ-PH 2 )} 2 Pt” (X=H, I) nuclear framework of the compounds." @default.
- W2320034086 created "2016-06-24" @default.
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- W2320034086 date "2005-03-01" @default.
- W2320034086 modified "2023-10-03" @default.
- W2320034086 title "From a 44-electron to a 48-electron trinuclear phosphido platinum complex: density functional study of [{(CF3)(PH3)Pt(μ-PH2)(μ-H)}2Pt] and [{(CF3)(PH3)Pt(μ-PH2)(μ-I)}2Pt] model compounds" @default.
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- W2320034086 doi "https://doi.org/10.1016/j.ica.2004.04.006" @default.
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