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• W2320043925 abstract "The recovery of gasoline vapor is still a major challenge in the petrochemical industry. In this study, a zeolitic imidazolate frameworks (ZIFs) membrane has been developed and first applied to gasoline vapor recovery. Zeolitic imidazole framework (ZIF-8) membranes were fabricated by a facile solvothermal seed growth method on ZrO2 supports. X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis measurements were conducted to study the morphologies, structure, and physical and chemical properties of ZIF-8 membranes. The effects of trans-membrane pressure drop, operating temperature, feed concentration, and stage cut on the separation performances of ZIF-8 membranes were systematically investigated. At 293 K, the ZIF-8 membrane showed an optimum n-hexane (n-C6H14) permeance of 7.16 × 10–8 mol/(m2·s·Pa) with the corresponding separation factor of 2.46 for the nitrogen/n-hexane model mixtures at a trans-membrane pressure drop of 0.05 MPa, a stage cut of 0.293, and a n-hexane volume fraction of 30%. Moreover, the separation factor for the multicomponent alkanes decreased with increasing the number of n-alkanes because of competitive adsorption of the n-alkanes in membrane pores. Experimental results indicated that the ZIF-8 membrane is a fairly promising candidate for the application in gasoline vapor recovery." @default.
• W2320043925 created "2016-06-24" @default.
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• W2320043925 date "2014-02-21" @default.
• W2320043925 modified "2023-09-29" @default.
• W2320043925 title "Study on the Development of ZIF-8 Membranes for Gasoline Vapor Recovery" @default.
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• W2320043925 doi "https://doi.org/10.1021/ie403894u" @default.
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