FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2320077277> ?p ?o ?g. }

• W2320077277 endingPage "15829" @default.
• W2320077277 startingPage "15823" @default.
• W2320077277 abstract "A complete mechanism for the proton-dependent electrocatalytic reduction of CO2 to CO by fac-Re(bpy)(CO)3Cl that is consistent with experimental observations has been developed using first principles quantum chemistry. Calculated one-electron reduction potentials, nonaqueous pKa’s, reaction free energies, and reaction barrier heights provide deep insight into the complex mechanism for CO2 reduction as well as the origin of selectivity for this catalyst. Protonation and then reduction of a metastable Re–CO2 intermediate anion precedes Brønsted-acid-catalyzed C–O cleavage and then rapid release of CO at negative applied potentials. Conceptually understanding the mechanism of this rapid catalytic process provides a useful blueprint for future work in artificial photosynthesis." @default.
• W2320077277 created "2016-06-24" @default.
• W2320077277 creator A5000007576 @default.
• W2320077277 creator A5007577939 @default.
• W2320077277 creator A5031776572 @default.
• W2320077277 creator A5090200106 @default.
• W2320077277 date "2013-10-09" @default.
• W2320077277 modified "2023-10-11" @default.
• W2320077277 title "Elucidation of the Selectivity of Proton-Dependent Electrocatalytic CO₂ Reduction by <i>fac</i>-Re(bpy)(CO)₃Cl" @default.
• W2320077277 cites W1964629102 @default.
• W2320077277 cites W1966729480 @default.
• W2320077277 cites W1969721273 @default.
• W2320077277 cites W1970655201 @default.
• W2320077277 cites W1974457621 @default.
• W2320077277 cites W1993545510 @default.
• W2320077277 cites W1997163291 @default.
• W2320077277 cites W1998337170 @default.
• W2320077277 cites W2002721385 @default.
• W2320077277 cites W2006420601 @default.
• W2320077277 cites W2008205705 @default.
• W2320077277 cites W2021770275 @default.
• W2320077277 cites W2022950330 @default.
• W2320077277 cites W2023271753 @default.
• W2320077277 cites W2027484986 @default.
• W2320077277 cites W2029667189 @default.
• W2320077277 cites W2030276680 @default.
• W2320077277 cites W2036452223 @default.
• W2320077277 cites W2037756241 @default.
• W2320077277 cites W2044586330 @default.
• W2320077277 cites W2050771666 @default.
• W2320077277 cites W2058848030 @default.
• W2320077277 cites W2063129680 @default.
• W2320077277 cites W2063404506 @default.
• W2320077277 cites W2065268072 @default.
• W2320077277 cites W2068617439 @default.
• W2320077277 cites W2069006374 @default.
• W2320077277 cites W2074292354 @default.
• W2320077277 cites W2077310850 @default.
• W2320077277 cites W2086957099 @default.
• W2320077277 cites W2091758842 @default.
• W2320077277 cites W2094642658 @default.
• W2320077277 cites W2095706733 @default.
• W2320077277 cites W2104980079 @default.
• W2320077277 cites W2124060104 @default.
• W2320077277 cites W2126688530 @default.
• W2320077277 cites W2129711615 @default.
• W2320077277 cites W2139978094 @default.
• W2320077277 cites W2147428684 @default.
• W2320077277 cites W2151357763 @default.
• W2320077277 cites W2154775028 @default.
• W2320077277 cites W2164318957 @default.
• W2320077277 cites W2167035995 @default.
• W2320077277 cites W2246944211 @default.
• W2320077277 cites W2314557938 @default.
• W2320077277 cites W2316710205 @default.
• W2320077277 cites W2332877952 @default.
• W2320077277 doi "https://doi.org/10.1021/ja406456g" @default.
• W2320077277 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24053131" @default.
• W2320077277 hasPublicationYear "2013" @default.
• W2320077277 type Work @default.
• W2320077277 sameAs 2320077277 @default.
• W2320077277 citedByCount "228" @default.
• W2320077277 countsByYear W23200772772013 @default.
• W2320077277 countsByYear W23200772772014 @default.
• W2320077277 countsByYear W23200772772015 @default.
• W2320077277 countsByYear W23200772772016 @default.
• W2320077277 countsByYear W23200772772017 @default.
• W2320077277 countsByYear W23200772772018 @default.
• W2320077277 countsByYear W23200772772019 @default.
• W2320077277 countsByYear W23200772772020 @default.
• W2320077277 countsByYear W23200772772021 @default.
• W2320077277 countsByYear W23200772772022 @default.
• W2320077277 countsByYear W23200772772023 @default.
• W2320077277 crossrefType "journal-article" @default.
• W2320077277 hasAuthorship W2320077277A5000007576 @default.
• W2320077277 hasAuthorship W2320077277A5007577939 @default.
• W2320077277 hasAuthorship W2320077277A5031776572 @default.
• W2320077277 hasAuthorship W2320077277A5090200106 @default.
• W2320077277 hasConcept C105768512 @default.
• W2320077277 hasConcept C118792377 @default.
• W2320077277 hasConcept C121332964 @default.
• W2320077277 hasConcept C123669783 @default.
• W2320077277 hasConcept C145148216 @default.
• W2320077277 hasConcept C147597530 @default.
• W2320077277 hasConcept C147789679 @default.
• W2320077277 hasConcept C161790260 @default.
• W2320077277 hasConcept C17525397 @default.
• W2320077277 hasConcept C178790620 @default.
• W2320077277 hasConcept C179104552 @default.
• W2320077277 hasConcept C185592680 @default.
• W2320077277 hasConcept C30095370 @default.
• W2320077277 hasConcept C33989665 @default.
• W2320077277 hasConcept C52859227 @default.
• W2320077277 hasConcept C54516573 @default.
• W2320077277 hasConcept C55904794 @default.
• W2320077277 hasConcept C62520636 @default.
• W2320077277 hasConcept C65024703 @default.
• W2320077277 hasConcept C75473681 @default.

• next