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- W2320121703 abstract "Metal-catalyzed addition of an O–H bond to an alkene is a desirable process because it allows for rapid access to ethers from abundant starting materials without the formation of waste, without rearrangements, and with the possibility to control the stereoselectivity. We report the intermolecular, metal-catalyzed addition of phenols to unactivated α-olefins. Mechanistic studies of this rare catalytic reaction revealed a dynamic mixture of resting states that undergo O–H bond oxidative addition and subsequent olefin insertion to form ether products." @default.
- W2320121703 created "2016-06-24" @default.
- W2320121703 creator A5046780195 @default.
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- W2320121703 date "2013-06-12" @default.
- W2320121703 modified "2023-10-18" @default.
- W2320121703 title "Iridium-Catalyzed, Intermolecular Hydroetherification of Unactivated Aliphatic Alkenes with Phenols" @default.
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- W2320121703 doi "https://doi.org/10.1021/ja4052153" @default.
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