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• W2320126443 abstract "Reaction of [RuCo(CO)3(μ-CO)(η-C5Me5){μ-η2:η2-C(CF3)C(CF3)}] (3) with alkenes gave the bis(vinyl) complexes [RuCo(CO)3(η-C5Me5){μ-η1:η2-C(CF3)CH(CF3)}(μ-η1:η2-CHCRH)] (4a, R = H; 4b, R = Me; 4c, R = CO2Me), through loss of carbon monoxide and via regiospecific alkene carbon−hydrogen bond activation. Low-temperature 13C{1H}, 1H, and 2D NMR spectroscopic studies of the reaction of 3 with ethene suggest the reaction proceeds via several coordinated ethene intermediates and a dimetallacyclic intermediate. Reaction of 3 with 1,1-dimethylallene resulted in carbon−carbon bond formation between the allene and alkyne, giving [RuCo(CO)3(η-C5Me5){μ-η2:η4-C(CF3)C(CF3)C(CMe2)(CH2)}] (5). The structures of [RuCo(CO)3(η-C5Me5){μ-η1:η2-C(CF3)CH(CF3)}(μ-η1:η2-CHCH2)] (4a), [RuCo(CO)3(η-C5Me5){μ-η1:η2-C(CF3)CH(CF3)}{μ-η1:η2-CHCH(CH3)}] (4b), and [RuCo(CO)3(η-C5Me5){μ-η2:η4-C(CF3)C(CF3)C(CMe2)(CH2)}] (5) have been determined by X-ray crystallographic studies." @default.
• W2320126443 created "2016-06-24" @default.
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• W2320126443 date "2004-08-17" @default.
• W2320126443 modified "2023-09-23" @default.
• W2320126443 title "Alkene Carbon−Hydrogen Bond Activation at a Heterobimetallic Center: [RuCo(CO)₃(μ-CO)(η-C₅Me₅){μ-η²:η²-C(CF₃)C(CF₃)}]" @default.
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• W2320126443 doi "https://doi.org/10.1021/om040026p" @default.
• W2320126443 hasPublicationYear "2004" @default.
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