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- W2320162010 abstract "Product selectivities both at early stage and thermodynamic equilibrium for the titled reaction were studied over silica-alumina and H-mordenite catalysts.For isopropylation with propylene over silica-alumina catalyst, 2-, 2'-, and 4-positions were more readily alkylated than 3-position at early stage of the reaction. After attaining thermodynamic equilibrium, the fraction of 3-isopropyl-p-terphenyl in the isomer mixture increased to 58%. On the other hand, the fraction of 4-isopropyl-p-terphenyl was 78% over the H-mordenite catalyst, due to the shape selectivity of H-mordenite, whereas it was 35-50% over the silica-alumina catalyst. The fraction of 4, 4-diisopropyl-p-terphenyl in the diisopropyl isomers was also as high as 75% over the H-mordenite catalyst, compared with 10-20% over the silica-alumina catalyst." @default.
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- W2320162010 date "1991-01-01" @default.
- W2320162010 modified "2023-09-23" @default.
- W2320162010 title "Isopropylation of p-Terphenyl over Solid Acid Catalysts." @default.
- W2320162010 doi "https://doi.org/10.1627/jpi1958.34.531" @default.
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