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• W2320312419 abstract "We report the room-temperature Raman spectra of polycrystalline Bi${}_{25}$InO${}_{39}$ for the first time along with the spectrum of Bi${}_{25}$FeO${}_{39}$. Both samples were synthesized by the conventional solid state method. The spectra of these compounds are remarkably similar to each other and those of other sillenites. A comparison of these sillenites, and others reported in the literature, shows that the Bi-O modes soften for compounds with larger (ionic radii) M cations. The widths of the modes increase for the compounds with larger M cations: the increase in width is attributed to inhomogeneous disorder in deviations of the Bi-O bond lengths across different unit cells. The results show that large M cations affect the Bi-O framework around the tetrahedron. The parameters of each Raman mode were obtained by fitting the spectral lines to a Lorentzian oscillator model, and the modes were assigned to symmetry-allowed vibrations of the $I$23 space group." @default.
• W2320312419 created "2016-06-24" @default.
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• W2320312419 date "2012-10-26" @default.
• W2320312419 modified "2023-10-13" @default.
• W2320312419 title "Raman spectroscopy evidence of inhomogeneous disorder in the bismuth-oxygen framework of Bi<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>25</mml:mn></mml:msub></mml:math>InO<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>39</mml:mn></mml:msub></mml:math>and other sillenites" @default.
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• W2320312419 doi "https://doi.org/10.1103/physrevb.86.144116" @default.
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