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• W2320328019 startingPage "6294" @default.
• W2320328019 abstract "A stream of 1–20 μm sized mineral inclusions having the negative crystal shape of its host within an “ultra-deep” diamond from Rio Soriso (Juina area, Mato Grosso State, Brazil) has been studied with confocal μ-X-ray absorption near edge structure (μXANES) at the Fe K and Mn K edges. This technique allows the three-dimensional nondestructive speciation of the Fe and Mn containing minerals within the inclusion cloud. The observed Fe-rich inclusions were identified to be ferropericlase (Fe,Mg)O, hematite and a mixture of these two minerals. Confocal μ-X-ray fluorescence (μXRF) further showed that Ca-rich inclusions were present as well, which are spatially separated from or in close contact with the Fe-rich inclusions. The inclusions are aligned along a plane, which most likely represents a primary growth zone. In the close vicinity of the inclusions, carbon coated planar features are visible. The three-dimensional distribution indicates a likely fluid overprint along an open crack. Our results imply that an imposed negative diamond shape of an inclusion alone does not exclude epigenetic formation or intense late stage overprint." @default.
• W2320328019 created "2016-06-24" @default.
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• W2320328019 date "2011-07-14" @default.
• W2320328019 modified "2023-10-14" @default.
• W2320328019 title "Three-Dimensional Fe Speciation of an Inclusion Cloud within an Ultradeep Diamond by Confocal μ-X-ray Absorption Near Edge Structure: Evidence for Late Stage Overprint" @default.
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• W2320328019 doi "https://doi.org/10.1021/ac201073s" @default.
• W2320328019 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21707095" @default.
• W2320328019 hasPublicationYear "2011" @default.
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