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• W2320333635 endingPage "951" @default.
• W2320333635 startingPage "948" @default.
• W2320333635 abstract "A counterion-controlled reactivity tuning in Pd-catalyzed highly chemoselective and regioselective dimerization and hydration of terminal alkynes is reported. The use of acetate as counterion favors the formation of an alkenyl alkynyl palladium intermediate which forms hitherto less reported 1,3-diaryl-substituted conjugated enynes after reductive elimination. Using chloride, which is a better leaving group, leads to anion exchange on the alkenylpalladium intermediate with hydroxide which after reductive elimination and tautomerization delivered the hydration products." @default.
• W2320333635 created "2016-06-24" @default.
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• W2320333635 date "2014-01-27" @default.
• W2320333635 modified "2023-09-29" @default.
• W2320333635 title "Reactivity Switch Enabled by Counterion: Highly Chemoselective Dimerization and Hydration of Terminal Alkynes" @default.
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• W2320333635 doi "https://doi.org/10.1021/ol403684a" @default.
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