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• W2320348805 abstract "Two inorganic–organic hybrid compounds with zero-dimensional crystal structures, tetramethylphosphonium tetrachloroferrate(III) (compound 1, [(CH3)4P][FeCl4]) and tetramethylphosphonium tetrabromoferrate(III) (compound 2, [(CH3)4P][FeBr4]), are discovered as multifunctional materials exhibiting simultaneously switchable dielectric, magnetic, and optical properties. Despite the analogue chemical formulas, compounds 1 and 2 crystallize in the different noncentrosymmetric space groups, that is, P63mc and F43m, and exhibit distinct responses in the three above-mentioned physical channels, especially for the magnetic property. Compound 1 undergoes dielectric anomalies which could be tuned in three distinct dielectric states and switched by the sequential phase transitions around 362 and 436 K, respectively. The symmetry breaking occurring during the first phase transition is confirmed by the switchable temperature-dependent second harmonic generation (SHG) effect. Weak antiferromagnetic interactions are also ..." @default.
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• W2320348805 date "2014-10-08" @default.
• W2320348805 modified "2023-10-02" @default.
• W2320348805 title "Novel Phase-Transition Materials Coupled with Switchable Dielectric, Magnetic, and Optical Properties: [(CH₃)₄P][FeCl₄] and [(CH₃)₄P][FeBr₄]" @default.
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• W2320348805 doi "https://doi.org/10.1021/cm503003f" @default.
• W2320348805 hasPublicationYear "2014" @default.
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