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• W2320371032 endingPage "929" @default.
• W2320371032 startingPage "920" @default.
• W2320371032 abstract "Abstract We have designed new trithiols Temp(SH) 3 and Tefp(SH) 3 that can be synthesized conveniently in short steps and are useful for preparation of crystalline [3:1] site‐differentiated [4Fe‐4S] clusters suitable for X‐ray structural analysis. The ethanethiolate clusters (PPh 4 ) 2 [Fe 4 S 4 (SEt)(TempS 3 )] ( 4a ) and (PPh 4 ) 2 [Fe 4 S 4 (SEt)(TefpS 3 )] ( 4b ) were prepared as precursors, and the unique iron sites were then selectively substituted. Upon reaction with H 2 S, (PPh 4 ) 2 [Fe 4 S 4 (SH)(TempS 3 )] ( 6a ) and (PPh 4 ) 2 [Fe 4 S 4 (SH)(TefpS 3 )] ( 6b ), which model the [4Fe‐4S] cluster in the β subunit of ( R )‐2‐hydroxyisocaproyl‐CoA dehydratase, were synthesized. Clusters 6a and 6b were further converted to the sulfido‐bridged double cubanes (PPh 4 ) 4 [{Fe 4 S 4 (TempS 3 )} 2 (μ 2 ‐S)] ( 6b ) and (PPh 4 ) 4 [{Fe 4 S 4 (TefpS 3 )} 2 (μ 2 ‐S)] ( 7b ), respectively, via intermolecular condensation with the release of H 2 S. Conversely, addition of H 2 S to 7a , 7b afforded the hydrosulfide clusters 6a , 6b . The molecular structures of the clusters reported herein were elucidated by X‐ray crystallographic analysis. Their redox properties were investigated by cyclic voltammetry." @default.
• W2320371032 created "2016-06-24" @default.
• W2320371032 creator A5031146180 @default.
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• W2320371032 creator A5090093816 @default.
• W2320371032 date "2012-04-05" @default.
• W2320371032 modified "2023-10-18" @default.
• W2320371032 title "Tridentate Thiolate Ligands: Application to the Synthesis of the Site-Differentiated [4Fe-4S] Cluster having a Hydrosulfide Ligand at the Unique Iron Center" @default.
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• W2320371032 cites W1965046245 @default.
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• W2320371032 cites W1971396352 @default.
• W2320371032 cites W1972588250 @default.
• W2320371032 cites W1973957235 @default.
• W2320371032 cites W1975769181 @default.
• W2320371032 cites W1977025440 @default.
• W2320371032 cites W1978144422 @default.
• W2320371032 cites W1983907122 @default.
• W2320371032 cites W1983925681 @default.
• W2320371032 cites W1989511619 @default.
• W2320371032 cites W1991228375 @default.
• W2320371032 cites W1991325941 @default.
• W2320371032 cites W1994103086 @default.
• W2320371032 cites W1998932788 @default.
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• W2320371032 cites W2007562082 @default.
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• W2320371032 cites W2007984633 @default.
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• W2320371032 cites W2032703523 @default.
• W2320371032 cites W2036300201 @default.
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• W2320371032 cites W2061484823 @default.
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• W2320371032 cites W2063102907 @default.
• W2320371032 cites W2067177570 @default.
• W2320371032 cites W2068606284 @default.
• W2320371032 cites W2069894935 @default.
• W2320371032 cites W2071183489 @default.
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• W2320371032 cites W2076242973 @default.
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• W2320371032 cites W2089293725 @default.
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• W2320371032 cites W2097682338 @default.
• W2320371032 cites W2113027556 @default.
• W2320371032 cites W2120233976 @default.
• W2320371032 cites W2128139794 @default.
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• W2320371032 doi "https://doi.org/10.1002/asia.201200039" @default.
• W2320371032 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22488788" @default.
• W2320371032 hasPublicationYear "2012" @default.
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