Matches in SemOpenAlex for { <https://semopenalex.org/work/W2320382539> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2320382539 endingPage "9443" @default.
- W2320382539 startingPage "9441" @default.
- W2320382539 abstract "The impact of solvent on electron transfer from Sm(II) to substrates was measured by determining the rate of reduction of 1-bromo-, 1-chlorododecane, and 3-pentanone in THF and hexanes using the highly soluble reductant {Sm[N(SiMe3)2]2(THF)2}. Rates were found to be 3 orders of magnitude faster in hexanes than THF, and reductions of alkyl halides were inverse first order in THF. These findings show the solvent milieu significantly impacts the rate of substrate reduction, a consideration that may prove useful in synthesis." @default.
- W2320382539 created "2016-06-24" @default.
- W2320382539 creator A5019999776 @default.
- W2320382539 creator A5072523681 @default.
- W2320382539 creator A5091690594 @default.
- W2320382539 date "2014-10-01" @default.
- W2320382539 modified "2023-10-01" @default.
- W2320382539 title "Solvent-Dependent Substrate Reduction by {Sm[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub>(THF)<sub>2</sub>}. An Alternative Approach for Accelerating the Rate of Substrate Reduction by Sm(II)" @default.
- W2320382539 cites W1963982778 @default.
- W2320382539 cites W1965440190 @default.
- W2320382539 cites W1976428217 @default.
- W2320382539 cites W1976742711 @default.
- W2320382539 cites W1990602726 @default.
- W2320382539 cites W1994423152 @default.
- W2320382539 cites W1997667290 @default.
- W2320382539 cites W2021168731 @default.
- W2320382539 cites W2034513553 @default.
- W2320382539 cites W2055630422 @default.
- W2320382539 cites W2067219178 @default.
- W2320382539 cites W2071181513 @default.
- W2320382539 cites W2082815458 @default.
- W2320382539 cites W2117829265 @default.
- W2320382539 cites W2120705954 @default.
- W2320382539 cites W2122145090 @default.
- W2320382539 cites W2146210199 @default.
- W2320382539 cites W2329382737 @default.
- W2320382539 cites W2330024285 @default.
- W2320382539 cites W2949249759 @default.
- W2320382539 cites W2950361650 @default.
- W2320382539 cites W2953381956 @default.
- W2320382539 doi "https://doi.org/10.1021/jo501819z" @default.
- W2320382539 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25255468" @default.
- W2320382539 hasPublicationYear "2014" @default.
- W2320382539 type Work @default.
- W2320382539 sameAs 2320382539 @default.
- W2320382539 citedByCount "12" @default.
- W2320382539 countsByYear W23203825392015 @default.
- W2320382539 countsByYear W23203825392016 @default.
- W2320382539 countsByYear W23203825392017 @default.
- W2320382539 countsByYear W23203825392018 @default.
- W2320382539 countsByYear W23203825392021 @default.
- W2320382539 countsByYear W23203825392022 @default.
- W2320382539 crossrefType "journal-article" @default.
- W2320382539 hasAuthorship W2320382539A5019999776 @default.
- W2320382539 hasAuthorship W2320382539A5072523681 @default.
- W2320382539 hasAuthorship W2320382539A5091690594 @default.
- W2320382539 hasConcept C111335779 @default.
- W2320382539 hasConcept C111368507 @default.
- W2320382539 hasConcept C127313418 @default.
- W2320382539 hasConcept C132439834 @default.
- W2320382539 hasConcept C155647269 @default.
- W2320382539 hasConcept C171560689 @default.
- W2320382539 hasConcept C178790620 @default.
- W2320382539 hasConcept C179104552 @default.
- W2320382539 hasConcept C185592680 @default.
- W2320382539 hasConcept C2524010 @default.
- W2320382539 hasConcept C2777289219 @default.
- W2320382539 hasConcept C2780263894 @default.
- W2320382539 hasConcept C2780471494 @default.
- W2320382539 hasConcept C33923547 @default.
- W2320382539 hasConceptScore W2320382539C111335779 @default.
- W2320382539 hasConceptScore W2320382539C111368507 @default.
- W2320382539 hasConceptScore W2320382539C127313418 @default.
- W2320382539 hasConceptScore W2320382539C132439834 @default.
- W2320382539 hasConceptScore W2320382539C155647269 @default.
- W2320382539 hasConceptScore W2320382539C171560689 @default.
- W2320382539 hasConceptScore W2320382539C178790620 @default.
- W2320382539 hasConceptScore W2320382539C179104552 @default.
- W2320382539 hasConceptScore W2320382539C185592680 @default.
- W2320382539 hasConceptScore W2320382539C2524010 @default.
- W2320382539 hasConceptScore W2320382539C2777289219 @default.
- W2320382539 hasConceptScore W2320382539C2780263894 @default.
- W2320382539 hasConceptScore W2320382539C2780471494 @default.
- W2320382539 hasConceptScore W2320382539C33923547 @default.
- W2320382539 hasFunder F4320337393 @default.
- W2320382539 hasIssue "20" @default.
- W2320382539 hasLocation W23203825391 @default.
- W2320382539 hasLocation W23203825392 @default.
- W2320382539 hasOpenAccess W2320382539 @default.
- W2320382539 hasPrimaryLocation W23203825391 @default.
- W2320382539 hasRelatedWork W1998761726 @default.
- W2320382539 hasRelatedWork W2082989531 @default.
- W2320382539 hasRelatedWork W2343582231 @default.
- W2320382539 hasRelatedWork W2762961497 @default.
- W2320382539 hasRelatedWork W2949226516 @default.
- W2320382539 hasRelatedWork W2949803813 @default.
- W2320382539 hasRelatedWork W2950649364 @default.
- W2320382539 hasRelatedWork W2951860203 @default.
- W2320382539 hasRelatedWork W2952782382 @default.
- W2320382539 hasRelatedWork W2952979462 @default.
- W2320382539 hasVolume "79" @default.
- W2320382539 isParatext "false" @default.
- W2320382539 isRetracted "false" @default.
- W2320382539 magId "2320382539" @default.
- W2320382539 workType "article" @default.