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- W2320404833 abstract "An abnormal or mesoionic N-heterocyclic carbene (NHC), namely 1,4-diphenyl-3-methyl-1,2,3-triazol-5-ylidene (Tz), formed from 1,4-diphenyl-3-methyl-1,2,3-triazolium iodide and silver oxide, gave the corresponding silver carbene complex. The transmetalation reaction of the silver carbene complex with PdCl2(CH3CN)2 gave a trans mononuclear complex, [(Tz)2PdCl2]. Reaction of the silver carbene complex with Pd(OAc)2 gave an acetate-bridged binuclear complex in which the palladium had undergone a C−H insertion at the ortho position of the phenyl group attached to the triazole nitrogen (1-position). The structures of these two complexes were established by single-crystal XRD data and spectroscopic data. The acetate complex was used as a catalyst for the stereoselective hydroarylation of alkynes." @default.
- W2320404833 created "2016-06-24" @default.
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- W2320404833 date "2011-02-28" @default.
- W2320404833 modified "2023-10-10" @default.
- W2320404833 title "Synthesis and Structure of 1,4-Diphenyl-3-methyl-1,2,3-triazol-5-ylidene Palladium Complexes and Application in Catalytic Hydroarylation of Alkynes" @default.
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- W2320404833 doi "https://doi.org/10.1021/om1011984" @default.
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