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• W2320424871 endingPage "9820" @default.
• W2320424871 startingPage "9810" @default.
• W2320424871 abstract "Cyclic amine or morpholine + organic solvent mixtures have been investigated in terms of DISQUAC and of the Kirkwood–Buff formalism. The amines considered are cyclohexylamine; (c-CH2)uNH (u = 2–7) and (c-CH2)uN–CH3 (u = 4,5). The organic solvents are alkanes and methanol or ethanol. The DISQUAC interaction parameters are reported. The model describes correctly a whole set of thermodynamic properties: vapor–liquid equilibria (VLE); excess Gibbs energies, GmE; excess enthalpies, HmE; excess heat capacities at constant pressure, CP,mE; and partial excess enthalpies at infinite dilution, H1E,∞, as well as the main features of the Kirkwood–Buff integrals. In (c-CH2)uNH + C6H12 mixtures, amine–amine interactions become weaker with increased u values. This is supported by the corresponding decrease of HmE and H1E,∞ and of the effective dipole moment. Interactions between amine molecules are also weakened when passing from a primary cyclic amine to an isomeric tertiary cyclic amine. The existence of an aromatic ring in the amine, as in aniline or pyridine, leads to stronger amine–amine interactions. Dipolar interactions between morpholine molecules are stronger than those between piperidine molecules, and reveal the existence of proximity effects between the two groups of morpholine. In systems with alkanes, interactions between amine molecules are preferred to those between unlike molecules. In piperidine + methanol and pyrrolidine + ethanol systems, the mixture structure is close to random mixing." @default.
• W2320424871 created "2016-06-24" @default.
• W2320424871 creator A5067619915 @default.
• W2320424871 date "2011-07-27" @default.
• W2320424871 modified "2023-09-27" @default.
• W2320424871 title "Thermodynamics of Mixtures Containing Amines. X. Systems with Cyclic Amines or Morpholine" @default.
• W2320424871 cites W1965576878 @default.
• W2320424871 cites W1965819763 @default.
• W2320424871 cites W1966451937 @default.
• W2320424871 cites W1968571296 @default.
• W2320424871 cites W1972517501 @default.
• W2320424871 cites W1973296467 @default.
• W2320424871 cites W1977254010 @default.
• W2320424871 cites W1977261788 @default.
• W2320424871 cites W1980520705 @default.
• W2320424871 cites W1982451752 @default.
• W2320424871 cites W1982651688 @default.
• W2320424871 cites W1985705561 @default.
• W2320424871 cites W1988833961 @default.
• W2320424871 cites W1990735413 @default.
• W2320424871 cites W1992944754 @default.
• W2320424871 cites W1996422639 @default.
• W2320424871 cites W1997493123 @default.
• W2320424871 cites W1997890206 @default.
• W2320424871 cites W2000510125 @default.
• W2320424871 cites W2000662914 @default.
• W2320424871 cites W2000773534 @default.
• W2320424871 cites W2001806976 @default.
• W2320424871 cites W2002832049 @default.
• W2320424871 cites W2003942417 @default.
• W2320424871 cites W2007895198 @default.
• W2320424871 cites W2009057123 @default.
• W2320424871 cites W2009983319 @default.
• W2320424871 cites W2012746233 @default.
• W2320424871 cites W2016239059 @default.
• W2320424871 cites W2017274527 @default.
• W2320424871 cites W2018653897 @default.
• W2320424871 cites W2019621216 @default.
• W2320424871 cites W2019990020 @default.
• W2320424871 cites W2020222470 @default.
• W2320424871 cites W2020961129 @default.
• W2320424871 cites W2022359006 @default.
• W2320424871 cites W2023590948 @default.
• W2320424871 cites W2024410348 @default.
• W2320424871 cites W2024492643 @default.
• W2320424871 cites W2026051242 @default.
• W2320424871 cites W2027722709 @default.
• W2320424871 cites W2029205115 @default.
• W2320424871 cites W2030069541 @default.
• W2320424871 cites W2036135869 @default.
• W2320424871 cites W2037222168 @default.
• W2320424871 cites W2043617098 @default.
• W2320424871 cites W2046543305 @default.
• W2320424871 cites W2048260932 @default.
• W2320424871 cites W2048347134 @default.
• W2320424871 cites W2050128109 @default.
• W2320424871 cites W2053432604 @default.
• W2320424871 cites W2053947818 @default.
• W2320424871 cites W2056282034 @default.
• W2320424871 cites W2060467622 @default.
• W2320424871 cites W2062634742 @default.
• W2320424871 cites W2064369224 @default.
• W2320424871 cites W2064702208 @default.
• W2320424871 cites W2066115018 @default.
• W2320424871 cites W2066525850 @default.
• W2320424871 cites W2067779719 @default.
• W2320424871 cites W2070720866 @default.
• W2320424871 cites W2073677067 @default.
• W2320424871 cites W2076712939 @default.
• W2320424871 cites W2077178437 @default.
• W2320424871 cites W2078748135 @default.
• W2320424871 cites W2083633934 @default.
• W2320424871 cites W2087943752 @default.
• W2320424871 cites W2089056353 @default.
• W2320424871 cites W2090218157 @default.
• W2320424871 cites W2091406601 @default.
• W2320424871 cites W2093806300 @default.
• W2320424871 cites W2094164763 @default.
• W2320424871 cites W2111393456 @default.
• W2320424871 cites W2112834459 @default.
• W2320424871 cites W2132941415 @default.
• W2320424871 cites W2145616060 @default.
• W2320424871 cites W2154433083 @default.
• W2320424871 cites W2170093630 @default.
• W2320424871 cites W2191484924 @default.
• W2320424871 cites W2573849077 @default.
• W2320424871 cites W2581476227 @default.
• W2320424871 cites W2621076591 @default.
• W2320424871 cites W2623161063 @default.
• W2320424871 cites W2624142000 @default.
• W2320424871 cites W269579827 @default.
• W2320424871 cites W2915784695 @default.
• W2320424871 cites W2917305752 @default.
• W2320424871 cites W2984254158 @default.
• W2320424871 cites W3043192494 @default.
• W2320424871 cites W4230092303 @default.
• W2320424871 cites W4231802547 @default.
• W2320424871 doi "https://doi.org/10.1021/ie201120h" @default.

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