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• W2320512063 abstract "The dinuclear Me2Pt(II) complexes of 3,4-bis(quinolin-8-yl)thiophene (1a), 3,4-bis(6 trifluoromethoxyquinolin-8-yl)thiophene (1b), and 3,4-bis(2-methylquinolin-8-yl)thiophene (1c) react with MeOTf (OTf = trifluoromethanesulfonate) to afford the corresponding chiral mononuclear five-coordinate Me3Pt(IV) complexes [PtMe3(1a)]OTf (3a), [PtMe3(1b)]OTf (3b), and [PtMe3(1c)]OTf (3c), respectively. [PtMe3(1c)]BArF4 (3d) (where BArF4 = [B{C6H3-3,5-(CF3)2}4]) has also been synthesized for structural study. While 3a appears to be symmetric in solution and asymmetric in solid state, 3c and 3d are asymmetric in both solution and solid state. The chirality originates from interligand repulsion, rather than any unsymmetrical ligand. Variable-temperature NMR and computational studies suggest a ligand-twisting isomerization pathway for the interconversion of the enantiomers, rather than the rotational exchange of three CH3 ligands on the metal center." @default.
• W2320512063 created "2016-06-24" @default.
• W2320512063 creator A5069244705 @default.
• W2320512063 creator A5069565621 @default.
• W2320512063 date "2011-10-12" @default.
• W2320512063 modified "2023-09-26" @default.
• W2320512063 title "Interconversion between the Enantiomers of Chiral Five-Coordinate Me₃Pt(IV) Complexes" @default.
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• W2320512063 doi "https://doi.org/10.1021/ic200889y" @default.
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