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- W2320513510 abstract "The solvates trans-[Mo(O)2(dppe)2]·2L (L = H2O, CH3OH, CH3CH2OH, CH3CHOHCH3) have been prepared by letting trans-[Mo(O)(F)(dppe)2](BF4) react with NEt4OH in mixtures of acetone and the respective hydrogen-bond donor solvents. This series of compounds is the first example of adduct formation between a trans-dioxo d2 metal complex and potential substrates for oxidation. These compounds can be protonated in two steps. The electronic spectra of the trans-oxo−hydroxo and trans-oxo−aqua species are consistent with the lowest energy transition being of dxy → {dzx,dyz} character." @default.
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- W2320513510 date "1997-06-01" @default.
- W2320513510 modified "2023-09-25" @default.
- W2320513510 title "Synthesis of <i>trans</i>-[Mo(O)(F)(dppe)<sub>2</sub>](BF<sub>4</sub>), <i>trans</i>-[Mo(O)(OH)(dppe)<sub>2</sub>](ClO<sub>4</sub>), and <i>trans</i>-[Mo(O)<sub>2</sub>(dppe)<sub>2</sub>]·2L (L = H<sub>2</sub>O, CH<sub>3</sub>OH, CH<sub>3</sub>CH<sub>2</sub>OH, CH<sub>3</sub>CHOHCH<sub>3</sub>). Crystal Structure of <i>trans</i>-[Mo(O)<sub>2</sub>(dppe)<sub>2</sub>]·2CH<sub>3</sub>OH" @default.
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- W2320513510 doi "https://doi.org/10.1021/ic9614071" @default.
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