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- W2320516377 abstract "Sc(OTf)3-catalyzed coupling reaction of silanediols with 2-methylallylsilanes and germanes leading to SiO–Si or SiO–Ge bond formation with the evolution of isobutylene is described. Diisopropyl-substituted silanediols of the general formula HO(i-Pr)2Si[OSi(i-Pr)2]nOH (n = 0,1) have been successfully functionalized by using 2-methylallylsilanes or 2-methylallylgermanes in the presence of scandium trifluoromethanesulfonate to yield new linear tri- and tetrasiloxanes or germasiloxanes under mild conditions. The reaction can be readily extended to the synthesis of high molecular weight polysiloxanes by using di(methylallyl)silane as a metalating agent. Unsaturated oligosiloxane products have been used as substrates for further functionalization via catalytic silylative coupling and hydrosilylation reactions." @default.
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- W2320516377 date "2013-08-19" @default.
- W2320516377 modified "2023-09-24" @default.
- W2320516377 title "Catalytic Synthesis of Linear Oligosiloxanes and Germasiloxanes Mediated by Scandium Trifluoromethanesulfonate" @default.
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- W2320516377 doi "https://doi.org/10.1021/om400581g" @default.
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