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• W2320565311 abstract "We present here two ligand classes based on a bis(pyrazolyl)methane scaffold functionalized with a rigid (-Ph-S-Ph) or flexible (-CH(2)-S-Ph) thioether function: L(R)PhS (R = H, Me) and L(R)CH(2)S (R = H, Me, iPr). The X-ray molecular structures of Ag(I) and Cu(I) binary complexes with L(R)PhS or L(R)CH(2)S using different types of counterions (BF(4)(-), PF(6)(-), and CF(3)SO(3)(-)) are reported. In these complexes, the ligands are N(2) bound on a metal center and bridge on a second metal with the thioether group. In contrast, when using triphenylphosphine (PPh(3)) as an ancillary ligand, mononuclear ternary complexes [M(L)PPh(3)](+) (M = Cu(I), Ag(I); L = L(R)PhS, L(R)CH(2)S) are formed. In these complexes, the more flexible ligand type, L(R)CH(2)S, is able to provide the N(2)S chelation, whereas the more rigid L(R)PhS ligand class is capable of chelating only N(2) because the thioether function preorganized, as it did in the coordination polymers, to point away from the metal center. Rigid potential-energy surface scans were performed by means of density functional theory (DFT) calculations (B3LYP/6-31+G) on the two representative ligands, L(H)PhS and L(H)CH(2)S. The surface scans proved that the thioether function is preferably oriented on the opposite side of the bispyrazole N(2) chelate system. These results confirm that both ligand classes are suitable components for the construction of coordination polymers. Nevertheless, the methylene group that acts as a spacer in L(H)CH(2)S imparts an inherent flexibility to this ligand class so that the conformation responsible for the N(2)S chelation is energetically accessible." @default.
• W2320565311 created "2016-06-24" @default.
• W2320565311 creator A5023170390 @default.
• W2320565311 creator A5038361271 @default.
• W2320565311 date "2011-10-03" @default.
• W2320565311 modified "2023-10-01" @default.
• W2320565311 title "Structural Variability in Ag(I) and Cu(I) Coordination Polymers with Thioether-Functionalized Bis(pyrazolyl)methane Ligands" @default.
• W2320565311 cites W1965272987 @default.
• W2320565311 cites W1967585041 @default.
• W2320565311 cites W1968242948 @default.
• W2320565311 cites W1969635440 @default.
• W2320565311 cites W1973687047 @default.
• W2320565311 cites W1973990981 @default.
• W2320565311 cites W1975217371 @default.
• W2320565311 cites W1975797915 @default.
• W2320565311 cites W1977761176 @default.
• W2320565311 cites W1979945615 @default.
• W2320565311 cites W1981184997 @default.
• W2320565311 cites W1981815885 @default.
• W2320565311 cites W1985352134 @default.
• W2320565311 cites W1987141277 @default.
• W2320565311 cites W1987181435 @default.
• W2320565311 cites W1988675344 @default.
• W2320565311 cites W1990520630 @default.
• W2320565311 cites W1993408779 @default.
• W2320565311 cites W1994938382 @default.
• W2320565311 cites W1995346641 @default.
• W2320565311 cites W1999339838 @default.
• W2320565311 cites W1999937609 @default.
• W2320565311 cites W2014038031 @default.
• W2320565311 cites W2015565771 @default.
• W2320565311 cites W2018885486 @default.
• W2320565311 cites W2021050313 @default.
• W2320565311 cites W2024056040 @default.
• W2320565311 cites W2029474347 @default.
• W2320565311 cites W2030618486 @default.
• W2320565311 cites W2030915780 @default.
• W2320565311 cites W2039598799 @default.
• W2320565311 cites W2042398645 @default.
• W2320565311 cites W2045007234 @default.
• W2320565311 cites W2050923105 @default.
• W2320565311 cites W2053167591 @default.
• W2320565311 cites W2056374761 @default.
• W2320565311 cites W2058125859 @default.
• W2320565311 cites W2058363175 @default.
• W2320565311 cites W2058363823 @default.
• W2320565311 cites W2061314082 @default.
• W2320565311 cites W2063011025 @default.
• W2320565311 cites W2063334178 @default.
• W2320565311 cites W2067038952 @default.
• W2320565311 cites W2067463371 @default.
• W2320565311 cites W2068905091 @default.
• W2320565311 cites W2069370875 @default.
• W2320565311 cites W2072894057 @default.
• W2320565311 cites W2076640232 @default.
• W2320565311 cites W2077246828 @default.
• W2320565311 cites W2078678890 @default.
• W2320565311 cites W2083686264 @default.
• W2320565311 cites W2086945873 @default.
• W2320565311 cites W2086957099 @default.
• W2320565311 cites W2091350409 @default.
• W2320565311 cites W2092792972 @default.
• W2320565311 cites W2094652646 @default.
• W2320565311 cites W2098411736 @default.
• W2320565311 cites W2100030276 @default.
• W2320565311 cites W2101093183 @default.
• W2320565311 cites W2112528885 @default.
• W2320565311 cites W2112974557 @default.
• W2320565311 cites W2116516840 @default.
• W2320565311 cites W2130122740 @default.
• W2320565311 cites W2137968851 @default.
• W2320565311 cites W2141603171 @default.
• W2320565311 cites W2143981217 @default.
• W2320565311 cites W2146063721 @default.
• W2320565311 cites W2146418534 @default.
• W2320565311 cites W2148140968 @default.
• W2320565311 cites W2156369098 @default.
• W2320565311 cites W2164776954 @default.
• W2320565311 cites W2335639035 @default.
• W2320565311 cites W4243158775 @default.
• W2320565311 doi "https://doi.org/10.1021/ic201338w" @default.
• W2320565311 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21967039" @default.
• W2320565311 hasPublicationYear "2011" @default.
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