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• W2320625878 abstract "With the goal of improving previously reported Mn bipyridine electrocatalysts in terms of increased activity and reduced overpotential, a bulky bipyridine ligand, 6,6'-dimesityl-2,2'-bipyridine (mesbpy), was utilized to eliminate dimerization in the catalytic cycle. Synthesis, electrocatalytic properties, X-ray diffraction (XRD) studies, and infrared spectroelectrochemistry (IR-SEC) of Mn(mesbpy)(CO)3Br and [Mn(mesbpy)(CO)3(MeCN)](OTf) are reported. Unlike previously reported Mn bipyridine catalysts, these Mn complexes exhibit a single, two-electron reduction wave under nitrogen, with no evidence of dimerization. The anionic complex, [Mn(mesbpy)(CO)3](-), is formed at 300 mV more positive potential than the corresponding state is formed in typical Mn bipyridine catalysts. IR-SEC experiments and chemical reductions with KC8 provide insights into the species leading up to the anionic state, specifically that both the singly reduced and doubly reduced Mn complexes form at the same potential. When formed, the anionic complex binds CO2 with H(+), but catalytic activity does not occur until a ~400 mV more negative potential is present. The Mn complexes show high activity and Faradaic efficiency for CO2 reduction to CO with the addition of weak Brønsted acids. IR-SEC experiments under CO2/H(+) indicate that reduction of a Mn(I)-CO2H catalytic intermediate may be the cause of this unusual over-reduction required to initiate catalysis." @default.
• W2320625878 created "2016-06-24" @default.
• W2320625878 creator A5000007576 @default.
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• W2320625878 creator A5083120910 @default.
• W2320625878 creator A5091742645 @default.
• W2320625878 date "2014-03-31" @default.
• W2320625878 modified "2023-10-16" @default.
• W2320625878 title "Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis" @default.
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• W2320625878 cites W1966729480 @default.
• W2320625878 cites W1967791195 @default.
• W2320625878 cites W1970655201 @default.
• W2320625878 cites W1973040261 @default.
• W2320625878 cites W1974659361 @default.
• W2320625878 cites W1975444637 @default.
• W2320625878 cites W1976140766 @default.
• W2320625878 cites W1990405306 @default.
• W2320625878 cites W1993545510 @default.
• W2320625878 cites W1997163291 @default.
• W2320625878 cites W1998337170 @default.
• W2320625878 cites W1998642713 @default.
• W2320625878 cites W2001831545 @default.
• W2320625878 cites W2005753110 @default.
• W2320625878 cites W2006420601 @default.
• W2320625878 cites W2006588706 @default.
• W2320625878 cites W2007484203 @default.
• W2320625878 cites W2008205705 @default.
• W2320625878 cites W2008614010 @default.
• W2320625878 cites W2008686504 @default.
• W2320625878 cites W2024382446 @default.
• W2320625878 cites W2030687437 @default.
• W2320625878 cites W2034759647 @default.
• W2320625878 cites W2036452223 @default.
• W2320625878 cites W2037529462 @default.
• W2320625878 cites W2038533471 @default.
• W2320625878 cites W2040506985 @default.
• W2320625878 cites W2042042522 @default.
• W2320625878 cites W2044343325 @default.
• W2320625878 cites W2044586330 @default.
• W2320625878 cites W2048375137 @default.
• W2320625878 cites W2049153025 @default.
• W2320625878 cites W2050462396 @default.
• W2320625878 cites W2050771666 @default.
• W2320625878 cites W2051154284 @default.
• W2320625878 cites W2054149576 @default.
• W2320625878 cites W2055770627 @default.
• W2320625878 cites W2056156555 @default.
• W2320625878 cites W2063404506 @default.
• W2320625878 cites W2065268072 @default.
• W2320625878 cites W2074292354 @default.
• W2320625878 cites W2075886178 @default.
• W2320625878 cites W2076072903 @default.
• W2320625878 cites W2077310850 @default.
• W2320625878 cites W2085566154 @default.
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• W2320625878 cites W2091758842 @default.
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• W2320625878 cites W2131350133 @default.
• W2320625878 cites W2139978094 @default.
• W2320625878 cites W2150345533 @default.
• W2320625878 cites W2150786833 @default.
• W2320625878 cites W2151357763 @default.
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• W2320625878 cites W2246944211 @default.
• W2320625878 cites W2320077277 @default.
• W2320625878 cites W2489179305 @default.
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• W2320625878 doi "https://doi.org/10.1021/ja501252f" @default.
• W2320625878 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25738737" @default.
• W2320625878 hasPublicationYear "2014" @default.
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