Matches in SemOpenAlex for { <https://semopenalex.org/work/W2320728110> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W2320728110 endingPage "2104" @default.
- W2320728110 startingPage "2093" @default.
- W2320728110 abstract "A method to access <i>cis</i>-3a-aryloctahydroindole alkaloids has been developed through a key strategy involving Eschenmoser–Claisen rearrangement of allylalcohol. This approach gives us an opportunity to access the all-carbon quaternary center required for <i>cis</i>-3a-aryloctahydroindole alkaloids. Subsequent simple allylic oxidation of Eschenmoser–Claisen products and synthetic elaborations (reductions/oxidations) enabled the total syntheses of the title compounds to be completed in good yields in a few steps. The strategic viability was further tested in the total syntheses of <i>Amaryllidaceae</i> alkaloids (±)-mesembrane and (±)-crinane. Towards this end, we synthesized advanced intermediate keto-aldehydes from Eschenmoser–Claisen rearrangement products through iodolactonization followed by elaboration involving reduction and oxidation steps." @default.
- W2320728110 created "2016-06-24" @default.
- W2320728110 creator A5029514541 @default.
- W2320728110 creator A5043183015 @default.
- W2320728110 creator A5046764792 @default.
- W2320728110 creator A5075785192 @default.
- W2320728110 date "2016-03-18" @default.
- W2320728110 modified "2023-10-10" @default.
- W2320728110 title "Concise Total Syntheses of (±)-Joubertiamine, (±)-O-Methyljoubertiamine, (±)-3′-Methoxy-4′-O-methyljoubertiamine, (±)-Mesembrane, and (±)-Crinane" @default.
- W2320728110 doi "https://doi.org/10.1055/s-0035-1561583" @default.
- W2320728110 hasPublicationYear "2016" @default.
- W2320728110 type Work @default.
- W2320728110 sameAs 2320728110 @default.
- W2320728110 citedByCount "8" @default.
- W2320728110 countsByYear W23207281102017 @default.
- W2320728110 countsByYear W23207281102018 @default.
- W2320728110 countsByYear W23207281102019 @default.
- W2320728110 countsByYear W23207281102020 @default.
- W2320728110 countsByYear W23207281102021 @default.
- W2320728110 crossrefType "journal-article" @default.
- W2320728110 hasAuthorship W2320728110A5029514541 @default.
- W2320728110 hasAuthorship W2320728110A5043183015 @default.
- W2320728110 hasAuthorship W2320728110A5046764792 @default.
- W2320728110 hasAuthorship W2320728110A5075785192 @default.
- W2320728110 hasConcept C120095180 @default.
- W2320728110 hasConcept C161790260 @default.
- W2320728110 hasConcept C178790620 @default.
- W2320728110 hasConcept C185592680 @default.
- W2320728110 hasConcept C2777667214 @default.
- W2320728110 hasConcept C2780567667 @default.
- W2320728110 hasConcept C2910425318 @default.
- W2320728110 hasConcept C35753019 @default.
- W2320728110 hasConcept C71240020 @default.
- W2320728110 hasConceptScore W2320728110C120095180 @default.
- W2320728110 hasConceptScore W2320728110C161790260 @default.
- W2320728110 hasConceptScore W2320728110C178790620 @default.
- W2320728110 hasConceptScore W2320728110C185592680 @default.
- W2320728110 hasConceptScore W2320728110C2777667214 @default.
- W2320728110 hasConceptScore W2320728110C2780567667 @default.
- W2320728110 hasConceptScore W2320728110C2910425318 @default.
- W2320728110 hasConceptScore W2320728110C35753019 @default.
- W2320728110 hasConceptScore W2320728110C71240020 @default.
- W2320728110 hasIssue "13" @default.
- W2320728110 hasLocation W23207281101 @default.
- W2320728110 hasOpenAccess W2320728110 @default.
- W2320728110 hasPrimaryLocation W23207281101 @default.
- W2320728110 hasRelatedWork W1961619173 @default.
- W2320728110 hasRelatedWork W1968818420 @default.
- W2320728110 hasRelatedWork W2035441700 @default.
- W2320728110 hasRelatedWork W2037689087 @default.
- W2320728110 hasRelatedWork W2099499994 @default.
- W2320728110 hasRelatedWork W2336357340 @default.
- W2320728110 hasRelatedWork W2761095392 @default.
- W2320728110 hasRelatedWork W2949850837 @default.
- W2320728110 hasRelatedWork W2950842142 @default.
- W2320728110 hasRelatedWork W2951841935 @default.
- W2320728110 hasVolume "48" @default.
- W2320728110 isParatext "false" @default.
- W2320728110 isRetracted "false" @default.
- W2320728110 magId "2320728110" @default.
- W2320728110 workType "article" @default.