FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2320735869> ?p ?o ?g. }

• W2320735869 endingPage "77" @default.
• W2320735869 startingPage "70" @default.
• W2320735869 abstract "The overall rate constants of hydroxyl radicals (OH) with ethylamine (EA: CH3CH2NH2) and dimethylamine (DMA: CH3NHCH3) were investigated behind reflected shock waves using UV laser absorption of OH radicals near 306.7 nm. tert-Butyl hydroperoxide (TBHP) was used as the fast source of OH at elevated temperatures. Test gas mixtures of individual amines and TBHP, diluted in argon, were shock-heated to temperatures from 901 to 1368 K at pressures near 1.2 atm. The overall rate constants were determined by fitting the measured OH time-histories with the computed profiles using a detailed mechanism developed by Lucassen et al. (Combust. Flame 2012, 159, 2254–2279). Over the temperature range studied, the measured rate constants can be expressed as kEA+OH = 1.10 × 107·T1.93 exp(1450/T) cm3 mol–1 s–1, and kDMA+OH = 2.26 × 104·T2.69 exp(1797/T) cm3 mol–1 s–1. Detailed error analyses were performed to estimate the overall uncertainties of the measured reaction rate constants, and the estimated (2σ) uncertainties were found to be ±31% at 901 K and ±22% at 1368 K for kEA+OH, and ±29% at 925 K and ±21% at 1307 K for kDMA+OH. Variational transition state theory was used to compute the H-abstraction rates by OH for ethylamine and dimethylamine, with the potential energy surface, geometries, frequencies, and electronic energies calculated by Galano and Alvarez-Idaboy (J. Chem. Theory Comput. 2008, 4, 322–327) at CCSD(T)/6-311++G(2d,2p) level of theory. The calculated reaction rate constants are in good agreement with the experimental data." @default.
• W2320735869 created "2016-06-24" @default.
• W2320735869 creator A5028789471 @default.
• W2320735869 creator A5039442806 @default.
• W2320735869 creator A5070606621 @default.
• W2320735869 creator A5090342502 @default.
• W2320735869 date "2013-12-19" @default.
• W2320735869 modified "2023-09-27" @default.
• W2320735869 title "High-Temperature Measurements of the Reactions of OH with Ethylamine and Dimethylamine" @default.
• W2320735869 cites W1515798186 @default.
• W2320735869 cites W1967788892 @default.
• W2320735869 cites W1968602577 @default.
• W2320735869 cites W1972247240 @default.
• W2320735869 cites W1976644981 @default.
• W2320735869 cites W1984423174 @default.
• W2320735869 cites W1985607756 @default.
• W2320735869 cites W1989211739 @default.
• W2320735869 cites W1992290252 @default.
• W2320735869 cites W1993944940 @default.
• W2320735869 cites W1995105379 @default.
• W2320735869 cites W1996441017 @default.
• W2320735869 cites W2017283575 @default.
• W2320735869 cites W2021629121 @default.
• W2320735869 cites W2034989340 @default.
• W2320735869 cites W2046001146 @default.
• W2320735869 cites W2046157084 @default.
• W2320735869 cites W2046952341 @default.
• W2320735869 cites W2050031678 @default.
• W2320735869 cites W2067064657 @default.
• W2320735869 cites W2073191019 @default.
• W2320735869 cites W2085714862 @default.
• W2320735869 cites W2086931301 @default.
• W2320735869 cites W2113881325 @default.
• W2320735869 cites W2119705547 @default.
• W2320735869 cites W2137115814 @default.
• W2320735869 cites W2159107979 @default.
• W2320735869 cites W2200464060 @default.
• W2320735869 cites W2312756295 @default.
• W2320735869 cites W2316943918 @default.
• W2320735869 cites W2318316267 @default.
• W2320735869 cites W4254456048 @default.
• W2320735869 doi "https://doi.org/10.1021/jp411141w" @default.
• W2320735869 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24328257" @default.
• W2320735869 hasPublicationYear "2013" @default.
• W2320735869 type Work @default.
• W2320735869 sameAs 2320735869 @default.
• W2320735869 citedByCount "17" @default.
• W2320735869 countsByYear W23207358692014 @default.
• W2320735869 countsByYear W23207358692015 @default.
• W2320735869 countsByYear W23207358692016 @default.
• W2320735869 countsByYear W23207358692017 @default.
• W2320735869 countsByYear W23207358692018 @default.
• W2320735869 countsByYear W23207358692019 @default.
• W2320735869 countsByYear W23207358692021 @default.
• W2320735869 countsByYear W23207358692022 @default.
• W2320735869 crossrefType "journal-article" @default.
• W2320735869 hasAuthorship W2320735869A5028789471 @default.
• W2320735869 hasAuthorship W2320735869A5039442806 @default.
• W2320735869 hasAuthorship W2320735869A5070606621 @default.
• W2320735869 hasAuthorship W2320735869A5090342502 @default.
• W2320735869 hasConcept C113196181 @default.
• W2320735869 hasConcept C121332964 @default.
• W2320735869 hasConcept C139066938 @default.
• W2320735869 hasConcept C147789679 @default.
• W2320735869 hasConcept C148898269 @default.
• W2320735869 hasConcept C178790620 @default.
• W2320735869 hasConcept C185592680 @default.
• W2320735869 hasConcept C2778678469 @default.
• W2320735869 hasConcept C2780825948 @default.
• W2320735869 hasConcept C3288061 @default.
• W2320735869 hasConcept C39353612 @default.
• W2320735869 hasConcept C62520636 @default.
• W2320735869 hasConcept C93391505 @default.
• W2320735869 hasConcept C97355855 @default.
• W2320735869 hasConceptScore W2320735869C113196181 @default.
• W2320735869 hasConceptScore W2320735869C121332964 @default.
• W2320735869 hasConceptScore W2320735869C139066938 @default.
• W2320735869 hasConceptScore W2320735869C147789679 @default.
• W2320735869 hasConceptScore W2320735869C148898269 @default.
• W2320735869 hasConceptScore W2320735869C178790620 @default.
• W2320735869 hasConceptScore W2320735869C185592680 @default.
• W2320735869 hasConceptScore W2320735869C2778678469 @default.
• W2320735869 hasConceptScore W2320735869C2780825948 @default.
• W2320735869 hasConceptScore W2320735869C3288061 @default.
• W2320735869 hasConceptScore W2320735869C39353612 @default.
• W2320735869 hasConceptScore W2320735869C62520636 @default.
• W2320735869 hasConceptScore W2320735869C93391505 @default.
• W2320735869 hasConceptScore W2320735869C97355855 @default.
• W2320735869 hasFunder F4320337480 @default.
• W2320735869 hasFunder F4320338281 @default.
• W2320735869 hasIssue "1" @default.
• W2320735869 hasLocation W23207358691 @default.
• W2320735869 hasLocation W23207358692 @default.
• W2320735869 hasOpenAccess W2320735869 @default.
• W2320735869 hasPrimaryLocation W23207358691 @default.
• W2320735869 hasRelatedWork W1982555277 @default.
• W2320735869 hasRelatedWork W2041347205 @default.
• W2320735869 hasRelatedWork W2056484796 @default.

• next