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- W2320764621 abstract "Although nitrogen and carbon monoxide differ very markedly in chemical behaviour, the physical properties of these gases are almost the same. This is because they have the same total number of electrons, almost the same molecular weight and the equilibrium distance between the nuclei differs only very little. Information from molecular spectra shows that the molecules have identical ground states; further the rotational and vibrational constants are remarkably alike. The centers of symmetry of the positive and negative charges in carbon monoxide do not coincide but the resulting dipole is very small (0.11 D). In the region of high densities differences persist (boiling point, melting point, density of the liquid and solid states, etc.). So far, no theoretical treatment of the differences has been attempted based on a detailed study of the intermolecular field." @default.
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- W2320764621 date "1955-01-01" @default.
- W2320764621 modified "2023-09-22" @default.
- W2320764621 title "Contribution to the Analysis of Molecular Interactions in Compressed Nitrogen and Carbon Monoxide" @default.
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- W2320764621 doi "https://doi.org/10.1007/978-94-017-5992-2_6" @default.
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