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- W2320794405 abstract "Abstract Tin oxide nanoparticles (SnO 2 NPs) have been encapsulated in situ in a three‐dimensional ordered space structure. Within this composite, ordered mesoporous carbon (OMC) acts as a carbon framework showing a desirable ordered mesoporous structure with an average pore size (≈6 nm) and a high surface area (470.3 m 2 g −1 ), and the SnO 2 NPs (≈10 nm) are highly loaded (up to 80 wt %) and homogeneously distributed within the OMC matrix. As an anode material for lithium‐ion batteries, a SnO 2 @OMC composite material can deliver an initial charge capacity of 943 mAh g −1 and retain 68.9 % of the initial capacity after 50 cycles at a current density of 50 mA g −1 , even exhibit a capacity of 503 mA h g −1 after 100 cycles at 160 mA g −1 . In situ encapsulation of the SnO 2 NPs within an OMC framework contributes to a higher capacity and a better cycling stability and rate capability in comparison with bare OMC and OMC ex situ loaded with SnO 2 particles (SnO 2 /OMC). The significantly improved electrochemical performance of the SnO 2 @OMC composite can be attributed to the multifunctional OMC matrix, which can facilitate electrolyte infiltration, accelerate charge transfer, and lithium‐ion diffusion, and act as a favorable buffer to release reaction strains for lithiation/delithiation of the SnO 2 NPs." @default.
- W2320794405 created "2016-06-24" @default.
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- W2320794405 date "2016-02-25" @default.
- W2320794405 modified "2023-10-12" @default.
- W2320794405 title "High-Loading Nano-SnO<sub>2</sub> Encapsulated in situ in Three-Dimensional Rigid Porous Carbon for Superior Lithium-Ion Batteries" @default.
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- W2320794405 doi "https://doi.org/10.1002/chem.201504420" @default.
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