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- W2321000580 abstract "We describe and develop an example of the successful application of a broadly applicable biomimetic growth process to the crystal growth of the complex inorganic quaternary high-temperature superconducting ceramic oxide YBa2Cu3O7−δ. By combining effective biopolymer mediation with established synthetic single crystal growth processes, we leverage a reduction in the required growth temperature from 1045 to 920 °C to enable the successful use of a molten salt synthesis technique in place of the high-temperature solution method commonly employed. Further, the influence of the biopolymer on the seed crystal nucleation provides for morphological control of the synthesis product, offering the potential for designed macromorphologies through biopolymer selection or customization. The method described is directly applicable to other difficult-to-synthesize materials that presently rely on similar conventional techniques, or for which such approaches have been found to fail, thereby providing a novel route to the successful bulk synthesis of complex refractory materials." @default.
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- W2321000580 date "2014-03-26" @default.
- W2321000580 modified "2023-10-18" @default.
- W2321000580 title "Biopolymer-Mediated Inorganic Crystal Growth at Reduced Temperature with Enhanced Kinetics and Morphological Direction" @default.
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- W2321000580 doi "https://doi.org/10.1021/cg401906g" @default.
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