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• W2321076056 endingPage "14569" @default.
• W2321076056 startingPage "14560" @default.
• W2321076056 abstract "A series of X(depe)2FeC≡C–C≡CFe(depe)2X complexes (depe =1,2-bis(diethylphosphino)ethane; X = I 1, NCMe 2, N2 3, C2H 4, C2SnMe3 5, C4SnMe3 6, NCSe 7, NCS 8, CN 9, SH 10, and NO2 11) was designed to study the influence of the anchor group on organometallic molecular transport junctions to achieve high-conductive molecular wires. The FeC4Fe core is electronically functional due to the redox-active Fe centers and sp-bridging ligands allowing a strong electronic delocalization. 1–11 were characterized by elemental analyses, X-ray diffraction, cyclic voltammetry, NMR, IR, and Raman spectroscopy. DFT calculations on model compounds gave the HOMO/LUMO energies. 5–9 were investigated in mechanically controllable break-junctions. For 9, unincisive features at 8.1 × 10–7 G0 indicate that sterical reasons prevent stable junctions to form or that the coordinative binding motif prohibits electron injection. 7 and 8 with the hitherto unexploited coordinatively binding end groups NCSe and NCS yielded currents of 1.3 × 10–9 A (7) and 1.8 × 10–10 A (8) at ±1.0 V. The SnMe3 in 5 and 6 splits off, yielding junctions with covalent C–Au bonds and currents of 6.5 × 10–7 A (Au–5′–Au) or 2.1 × 10–7 A (Au–6′–Au). Despite of a length of almost 2 nm, the Au–5′–Au junction reaches 1% of the maximum current assuming one conductance channel in quantum point contacts. Additionally, the current noise in the transport data is considerably reduced for the covalent C–Au coupling compared to the coordinative anchoring of 7–9, endorsing C–Au coupled organometallic complexes as excellent candidates for low-ohmic molecular wires." @default.
• W2321076056 created "2016-06-24" @default.
• W2321076056 creator A5001324799 @default.
• W2321076056 creator A5003476481 @default.
• W2321076056 creator A5011276051 @default.
• W2321076056 creator A5041097915 @default.
• W2321076056 creator A5047826736 @default.
• W2321076056 creator A5048723309 @default.
• W2321076056 creator A5062674895 @default.
• W2321076056 date "2014-10-02" @default.
• W2321076056 modified "2023-10-18" @default.
• W2321076056 title "Organometallic Single-Molecule Electronics: Tuning Electron Transport through X(diphosphine)₂FeC₄Fe(diphosphine)₂X Building Blocks by Varying the Fe–X–Au Anchoring Scheme from Coordinative to Covalent" @default.
• W2321076056 cites W1966182479 @default.
• W2321076056 cites W1966220862 @default.
• W2321076056 cites W1968732229 @default.
• W2321076056 cites W1969336106 @default.
• W2321076056 cites W1971275758 @default.
• W2321076056 cites W1971944253 @default.
• W2321076056 cites W1973686723 @default.
• W2321076056 cites W1974599100 @default.
• W2321076056 cites W1975708211 @default.
• W2321076056 cites W1976344782 @default.
• W2321076056 cites W1977152045 @default.
• W2321076056 cites W1977592516 @default.
• W2321076056 cites W1979802434 @default.
• W2321076056 cites W1985178158 @default.
• W2321076056 cites W1986050269 @default.
• W2321076056 cites W1990608394 @default.
• W2321076056 cites W1994074263 @default.
• W2321076056 cites W1995195523 @default.
• W2321076056 cites W1996031611 @default.
• W2321076056 cites W1999292430 @default.
• W2321076056 cites W1999301101 @default.
• W2321076056 cites W2001675098 @default.
• W2321076056 cites W2005197716 @default.
• W2321076056 cites W2007127115 @default.
• W2321076056 cites W2007543119 @default.
• W2321076056 cites W2009852209 @default.
• W2321076056 cites W2014126110 @default.
• W2321076056 cites W2014459414 @default.
• W2321076056 cites W2025856066 @default.
• W2321076056 cites W2028466864 @default.
• W2321076056 cites W2028856433 @default.
• W2321076056 cites W2029132601 @default.
• W2321076056 cites W2031223934 @default.
• W2321076056 cites W2034402791 @default.
• W2321076056 cites W2037489527 @default.
• W2321076056 cites W2037791410 @default.
• W2321076056 cites W2040865037 @default.
• W2321076056 cites W2043887052 @default.
• W2321076056 cites W2044490585 @default.
• W2321076056 cites W2045725637 @default.
• W2321076056 cites W2046046698 @default.
• W2321076056 cites W2047776614 @default.
• W2321076056 cites W2049136499 @default.
• W2321076056 cites W2049381652 @default.
• W2321076056 cites W2053489433 @default.
• W2321076056 cites W2055550841 @default.
• W2321076056 cites W2056381273 @default.
• W2321076056 cites W2059205366 @default.
• W2321076056 cites W2063334178 @default.
• W2321076056 cites W2066591454 @default.
• W2321076056 cites W2067367392 @default.
• W2321076056 cites W2068450541 @default.
• W2321076056 cites W2068617439 @default.
• W2321076056 cites W2075381847 @default.
• W2321076056 cites W2081062251 @default.
• W2321076056 cites W2085302815 @default.
• W2321076056 cites W2088021124 @default.
• W2321076056 cites W2088481620 @default.
• W2321076056 cites W2089763792 @default.
• W2321076056 cites W2091768109 @default.
• W2321076056 cites W2113836380 @default.
• W2321076056 cites W2131350133 @default.
• W2321076056 cites W2133580852 @default.
• W2321076056 cites W2143009339 @default.
• W2321076056 cites W2147294959 @default.
• W2321076056 cites W2148469323 @default.
• W2321076056 cites W2149795011 @default.
• W2321076056 cites W2160737217 @default.
• W2321076056 cites W2166422781 @default.
• W2321076056 cites W2166689829 @default.
• W2321076056 cites W2168968360 @default.
• W2321076056 cites W2170240450 @default.
• W2321076056 cites W2170411914 @default.
• W2321076056 cites W2212499008 @default.
• W2321076056 cites W2312608961 @default.
• W2321076056 cites W2315398652 @default.
• W2321076056 cites W2321236141 @default.
• W2321076056 cites W2321932525 @default.
• W2321076056 cites W2327220970 @default.
• W2321076056 cites W2329527515 @default.
• W2321076056 cites W2333772398 @default.
• W2321076056 cites W2334809931 @default.
• W2321076056 cites W2503005323 @default.
• W2321076056 cites W32310619 @default.
• W2321076056 cites W4213218636 @default.
• W2321076056 cites W4254640185 @default.

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