FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321218557> ?p ?o ?g. }

• W2321218557 endingPage "6072" @default.
• W2321218557 startingPage "6066" @default.
• W2321218557 abstract "Experiments were performed on nitrobenzene liquid at ambient temperature to probe vibrational energy flow from the nitro group to the phenyl group and vice versa. The IR pump, Raman probe method was used. Quantum chemical calculations were used to sort the normal modes of nitrobenzene into three categories: phenyl modes, nitro modes, and global modes. IR wavelengths in the 2500–3500 cm–1 range were found that best produced excitations initially localized on nitro or phenyl. Pulses at 2880 cm–1 excited a nitro stretch combination band. Pulses at 3080 cm–1 excited a phenyl C–H stretch plus some nitro stretch. With nitro excitation there was no detectable energy transfer to phenyl. With phenyl excitation there was no direct transfer to nitro, but there was some transfer to global modes such as phenyl-nitro stretching, so some of the vibrational amplitude on phenyl moved onto nitro. Thus energy transfer from nitro to phenyl was absent, but there was weak energy transfer from phenyl to nitro. The experimental methods described here can be used to study vibrational energy flow from one part of a molecule to another, which could assist in the design of molecules for molecular electronics and phononics. The vibrational isolation of the nitro group when attached to a phenyl moiety suggests that strongly nonthermal reaction pathways may play an important role in impact initiation of energetic materials having peripheral nitro groups." @default.
• W2321218557 created "2016-06-24" @default.
• W2321218557 creator A5017016982 @default.
• W2321218557 creator A5032565369 @default.
• W2321218557 creator A5075047143 @default.
• W2321218557 date "2013-03-07" @default.
• W2321218557 modified "2023-10-11" @default.
• W2321218557 title "Unidirectional Vibrational Energy Flow in Nitrobenzene" @default.
• W2321218557 cites W1968587238 @default.
• W2321218557 cites W1972641719 @default.
• W2321218557 cites W1973175777 @default.
• W2321218557 cites W1974478048 @default.
• W2321218557 cites W1991836553 @default.
• W2321218557 cites W2011041258 @default.
• W2321218557 cites W2012482788 @default.
• W2321218557 cites W2012770527 @default.
• W2321218557 cites W2013882566 @default.
• W2321218557 cites W2018822273 @default.
• W2321218557 cites W2025995035 @default.
• W2321218557 cites W2031135800 @default.
• W2321218557 cites W2037311879 @default.
• W2321218557 cites W2040292140 @default.
• W2321218557 cites W2041759250 @default.
• W2321218557 cites W2043542716 @default.
• W2321218557 cites W2044038906 @default.
• W2321218557 cites W2044326923 @default.
• W2321218557 cites W2056851814 @default.
• W2321218557 cites W2058134096 @default.
• W2321218557 cites W2058477232 @default.
• W2321218557 cites W2064227131 @default.
• W2321218557 cites W2064860068 @default.
• W2321218557 cites W2069614700 @default.
• W2321218557 cites W2071964271 @default.
• W2321218557 cites W2084380236 @default.
• W2321218557 cites W2085429919 @default.
• W2321218557 cites W2086278991 @default.
• W2321218557 cites W2086778233 @default.
• W2321218557 cites W2088249947 @default.
• W2321218557 cites W2089471774 @default.
• W2321218557 cites W2094306059 @default.
• W2321218557 cites W2120407342 @default.
• W2321218557 cites W2141070669 @default.
• W2321218557 cites W2142549589 @default.
• W2321218557 cites W2144844311 @default.
• W2321218557 cites W2312608662 @default.
• W2321218557 cites W2315038384 @default.
• W2321218557 cites W2318051463 @default.
• W2321218557 cites W2493636780 @default.
• W2321218557 cites W2950952956 @default.
• W2321218557 cites W3104792176 @default.
• W2321218557 cites W4250327347 @default.
• W2321218557 doi "https://doi.org/10.1021/jp3127863" @default.
• W2321218557 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23432106" @default.
• W2321218557 hasPublicationYear "2013" @default.
• W2321218557 type Work @default.
• W2321218557 sameAs 2321218557 @default.
• W2321218557 citedByCount "47" @default.
• W2321218557 countsByYear W23212185572013 @default.
• W2321218557 countsByYear W23212185572014 @default.
• W2321218557 countsByYear W23212185572015 @default.
• W2321218557 countsByYear W23212185572016 @default.
• W2321218557 countsByYear W23212185572017 @default.
• W2321218557 countsByYear W23212185572018 @default.
• W2321218557 countsByYear W23212185572019 @default.
• W2321218557 countsByYear W23212185572020 @default.
• W2321218557 countsByYear W23212185572021 @default.
• W2321218557 countsByYear W23212185572022 @default.
• W2321218557 countsByYear W23212185572023 @default.
• W2321218557 crossrefType "journal-article" @default.
• W2321218557 hasAuthorship W2321218557A5017016982 @default.
• W2321218557 hasAuthorship W2321218557A5032565369 @default.
• W2321218557 hasAuthorship W2321218557A5075047143 @default.
• W2321218557 hasConcept C119599485 @default.
• W2321218557 hasConcept C120665830 @default.
• W2321218557 hasConcept C121332964 @default.
• W2321218557 hasConcept C127413603 @default.
• W2321218557 hasConcept C147597530 @default.
• W2321218557 hasConcept C161790260 @default.
• W2321218557 hasConcept C178790620 @default.
• W2321218557 hasConcept C181500209 @default.
• W2321218557 hasConcept C184779094 @default.
• W2321218557 hasConcept C185592680 @default.
• W2321218557 hasConcept C2776568683 @default.
• W2321218557 hasConcept C2777327210 @default.
• W2321218557 hasConcept C2780263894 @default.
• W2321218557 hasConcept C2780554229 @default.
• W2321218557 hasConcept C2780639532 @default.
• W2321218557 hasConcept C2780809723 @default.
• W2321218557 hasConcept C32909587 @default.
• W2321218557 hasConcept C40003534 @default.
• W2321218557 hasConcept C41999313 @default.
• W2321218557 hasConcept C71240020 @default.
• W2321218557 hasConcept C75473681 @default.
• W2321218557 hasConcept C83581075 @default.
• W2321218557 hasConceptScore W2321218557C119599485 @default.
• W2321218557 hasConceptScore W2321218557C120665830 @default.
• W2321218557 hasConceptScore W2321218557C121332964 @default.
• W2321218557 hasConceptScore W2321218557C127413603 @default.

• next