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- W2321359098 abstract "Abstract N-Unsubstituted sulfilimines, when reacted with sodium hypochlorite in an aqueous alkaline methanol solution or with Chloramine-T in dry acetonitrile in the presence of excess sodium salt of tosylamide were converted to the corresponding N-unsubstituted sulfoximines (1) or mono-N-tosylsulfonediimines (2) in good yields. 2 gave the unsubstituted sulfonediimines (3) in high yields upon treatment with conc. H2SO4. N-Chlorosulfilimine (5) was isolated in the initial stage of these reactions. 5 was found to react with NaOH in aqueous methanol and also with anhydrous Chloramine-T in dry acetonitrile to yield the corresponding 1 and 2 in good yields. IR, NMR, and Mass spectroscopic studies of 1, 2, and 3 were also carried out." @default.
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- W2321359098 date "1984-06-01" @default.
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- W2321359098 title "CONVENIENT PREPARATION AND SPECTROSCOPIC STUDIES OF SULFOXIMINES AND SULFONEDIIMINES:<i>N</i>-CHLOROSULFILIMINE AS KEY INTERMEDIATE" @default.
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- W2321359098 doi "https://doi.org/10.1080/03086648408077606" @default.
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