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• W2321396989 startingPage "10262" @default.
• W2321396989 abstract "The synthesis of a three-coordinate Pt-borane complex featuring a bidentate LZ (boryl)iminomethane (BIM) ligand is reported. Unlike other LZ-type borane ligands featuring a single-donor buttress, the small bite angle enforced by the BIM ligand is shown to promote a significant metal-borane reverse-dative σ-interaction akin to multiply strapped metalloboratranes. The steric accessibility of the reactive Pt → B bond fostered by the BIM ligand allows for a rich reactivity profile toward small molecules that exploit metal-borane cooperative effects. The unligated (boryl)iminomethane BIM is also synthetically accessible and functions as a Frustrated Lewis Pair (FLP). The ability of the free BIM to effect bond activation reactions is contrasted with the behavior seen in the corresponding platinum-bound complexes." @default.
• W2321396989 created "2016-06-24" @default.
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• W2321396989 date "2014-07-15" @default.
• W2321396989 modified "2023-09-29" @default.
• W2321396989 title "Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate" @default.
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• W2321396989 doi "https://doi.org/10.1021/ja505843g" @default.
• W2321396989 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25007258" @default.
• W2321396989 hasPublicationYear "2014" @default.
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