Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321485213> ?p ?o ?g. }
- W2321485213 endingPage "5796" @default.
- W2321485213 startingPage "5787" @default.
- W2321485213 abstract "We studied the thermodynamic properties of ion solvation in polymer blends and block copolymer melts and developed a dipolar self-consistent field theory for polymer mixtures. Our theory accounts for the chain connectivity of polymerized monomers, the compressibility of the liquid mixtures under electrostriction, the permanent and induced dipole moments of monomers, and the resultant dielectric contrast among species. In our coarse-grained model, dipoles are attached to the monomers and allowed to rotate freely in response to electrostatic fields. We demonstrate that a strong electrostatic field near an ion reorganizes dipolar monomers, resulting in nonmonotonic changes in the volume fraction profile and the dielectric function of the polymers with respect to those of simple liquid mixtures. For the parameter sets used, the spatial variations near an ion can be in the range of 1 nm or larger, producing significant differences in the solvation energy among simple liquid mixtures, polymer blends, and block copolymers. The solvation energy of an ion depends substantially on the chain length in block copolymers; thus, our theory predicts the preferential solvation of ions arising from differences in chain length." @default.
- W2321485213 created "2016-06-24" @default.
- W2321485213 creator A5083539979 @default.
- W2321485213 date "2014-05-15" @default.
- W2321485213 modified "2023-09-27" @default.
- W2321485213 title "Ion Solvation in Polymer Blends and Block Copolymer Melts: Effects of Chain Length and Connectivity on the Reorganization of Dipoles" @default.
- W2321485213 cites W1949231392 @default.
- W2321485213 cites W1964582672 @default.
- W2321485213 cites W1969269696 @default.
- W2321485213 cites W1970495824 @default.
- W2321485213 cites W1971404879 @default.
- W2321485213 cites W1980584915 @default.
- W2321485213 cites W1982061903 @default.
- W2321485213 cites W1983922143 @default.
- W2321485213 cites W1984147471 @default.
- W2321485213 cites W1991263911 @default.
- W2321485213 cites W1993190277 @default.
- W2321485213 cites W2003201699 @default.
- W2321485213 cites W2012986398 @default.
- W2321485213 cites W2018729763 @default.
- W2321485213 cites W2022047868 @default.
- W2321485213 cites W2022849802 @default.
- W2321485213 cites W2024293617 @default.
- W2321485213 cites W2024561699 @default.
- W2321485213 cites W2029293256 @default.
- W2321485213 cites W2032483121 @default.
- W2321485213 cites W2056267512 @default.
- W2321485213 cites W2056809800 @default.
- W2321485213 cites W2060212880 @default.
- W2321485213 cites W2075953307 @default.
- W2321485213 cites W2076047144 @default.
- W2321485213 cites W2078997684 @default.
- W2321485213 cites W2086342280 @default.
- W2321485213 cites W2091051349 @default.
- W2321485213 cites W2091248344 @default.
- W2321485213 cites W2094709211 @default.
- W2321485213 cites W2169672069 @default.
- W2321485213 cites W2326203395 @default.
- W2321485213 cites W2326537980 @default.
- W2321485213 cites W2329330520 @default.
- W2321485213 cites W2329398431 @default.
- W2321485213 cites W2330842273 @default.
- W2321485213 cites W2331833084 @default.
- W2321485213 cites W2335219556 @default.
- W2321485213 cites W2963402464 @default.
- W2321485213 cites W2963785841 @default.
- W2321485213 cites W3098413561 @default.
- W2321485213 cites W3101549204 @default.
- W2321485213 cites W4230257048 @default.
- W2321485213 doi "https://doi.org/10.1021/jp502987a" @default.
- W2321485213 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24806716" @default.
- W2321485213 hasPublicationYear "2014" @default.
- W2321485213 type Work @default.
- W2321485213 sameAs 2321485213 @default.
- W2321485213 citedByCount "24" @default.
- W2321485213 countsByYear W23214852132014 @default.
- W2321485213 countsByYear W23214852132015 @default.
- W2321485213 countsByYear W23214852132016 @default.
- W2321485213 countsByYear W23214852132017 @default.
- W2321485213 countsByYear W23214852132018 @default.
- W2321485213 countsByYear W23214852132019 @default.
- W2321485213 countsByYear W23214852132020 @default.
- W2321485213 countsByYear W23214852132021 @default.
- W2321485213 countsByYear W23214852132022 @default.
- W2321485213 crossrefType "journal-article" @default.
- W2321485213 hasAuthorship W2321485213A5083539979 @default.
- W2321485213 hasConcept C121332964 @default.
- W2321485213 hasConcept C133386390 @default.
- W2321485213 hasConcept C145148216 @default.
- W2321485213 hasConcept C148093993 @default.
- W2321485213 hasConcept C15920480 @default.
- W2321485213 hasConcept C159467904 @default.
- W2321485213 hasConcept C159985019 @default.
- W2321485213 hasConcept C166940927 @default.
- W2321485213 hasConcept C173523689 @default.
- W2321485213 hasConcept C178790620 @default.
- W2321485213 hasConcept C185592680 @default.
- W2321485213 hasConcept C192562407 @default.
- W2321485213 hasConcept C49040817 @default.
- W2321485213 hasConcept C521977710 @default.
- W2321485213 hasConcept C97355855 @default.
- W2321485213 hasConceptScore W2321485213C121332964 @default.
- W2321485213 hasConceptScore W2321485213C133386390 @default.
- W2321485213 hasConceptScore W2321485213C145148216 @default.
- W2321485213 hasConceptScore W2321485213C148093993 @default.
- W2321485213 hasConceptScore W2321485213C15920480 @default.
- W2321485213 hasConceptScore W2321485213C159467904 @default.
- W2321485213 hasConceptScore W2321485213C159985019 @default.
- W2321485213 hasConceptScore W2321485213C166940927 @default.
- W2321485213 hasConceptScore W2321485213C173523689 @default.
- W2321485213 hasConceptScore W2321485213C178790620 @default.
- W2321485213 hasConceptScore W2321485213C185592680 @default.
- W2321485213 hasConceptScore W2321485213C192562407 @default.
- W2321485213 hasConceptScore W2321485213C49040817 @default.
- W2321485213 hasConceptScore W2321485213C521977710 @default.
- W2321485213 hasConceptScore W2321485213C97355855 @default.
- W2321485213 hasIssue "21" @default.
- W2321485213 hasLocation W23214852131 @default.