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- W2321495972 abstract "A highly enantioselective rhodium(I)-catalyzed dearomative arylation or alkenylation of easily available N-alkylquinolinium salts is reported, thus providing an effective and practical approach to the synthesis of dihydroquinolines in up to 99 % ee. This reaction tolerates a wide range of functional groups with respect to both the organic boronic acids and the quinoline starting materials. Moreover, the synthetic utility of this protocol is demonstrated in the formal asymmetric synthesis of bioactive tetrahydroquinoline and the total syntheses of (-)-angustureine and (+)-cuspareine." @default.
- W2321495972 created "2016-06-24" @default.
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- W2321495972 date "2016-02-16" @default.
- W2321495972 modified "2023-10-15" @default.
- W2321495972 title "Enantioselective Rhodium-Catalyzed Dearomative Arylation or Alkenylation of Quinolinium Salts" @default.
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- W2321495972 doi "https://doi.org/10.1002/anie.201511663" @default.
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