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- W2321507523 endingPage "3980" @default.
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- W2321507523 abstract "Abstract An unusual reactivity of 2‐(1‐alkenyl)‐pyridines towards hydroboration with 9 H ‐borabicyclo[3.3.1]nonane (9 H ‐BBN) has been employed to selectively introduce two borane groups into a conjugated quaterpyridine. Quantitative conversion of the substrate was observed with exclusive regioselectivity. A molecular structure that allows intramolecular N→B coordination was generated. The effect of the ladder formation on the molecular structure and the electronic properties of the conjugated system have been investigated. The synthetic strategy demonstrated herein offers a facile access to N→B ladder‐type structures from readily available substrates, and allows to simultaneously introduce several boron centers under mild conditions." @default.
- W2321507523 created "2016-06-24" @default.
- W2321507523 creator A5053311253 @default.
- W2321507523 creator A5061169654 @default.
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- W2321507523 date "2016-02-11" @default.
- W2321507523 modified "2023-09-25" @default.
- W2321507523 title "Generation of an N→B Ladder-type Structure by Regioselective Hydroboration of an Alkenyl-Functionalized Quaterpyridine" @default.
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- W2321507523 doi "https://doi.org/10.1002/chem.201600228" @default.
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