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- W2321548556 abstract "Large-pore ethenylene-bridged (−CH═CH−) and phenylene-bridged (−C6H4−) periodic mesoporous organosilicas (PMOs) with face-centered-cubic structure (Fm3m symmetry) of spherical mesopores were synthesized at 7 °C at low acid concentration (0.1 M HCl) using Pluronic F127 triblock copolymer surfactant in the presence of aromatic swelling agents (1,3,5-trimethylbenzene, xylenes–isomer mixture, and toluene). In particular, this work reports an unprecedented block-copolymer-templated well-ordered ethenylene-bridged PMO with cubic structure of spherical mesopores and an unprecedented block-copolymer-templated face-centered cubic phenylene-bridged PMO, which also has an exceptionally large unit-cell size and pore diameter. The unit-cell parameters of 30 and 25 nm and the mesopore diameters of 14 and 11 nm (nominal BJH-KJS pore diameters of 12–13 and 9 nm) were obtained for ethenylene-bridged and phenylene-bridged PMOs, respectively. Under the considered reaction conditions, the unit-cell parameters and pore diameters were found to be similar when the three different methyl-substituted benzene swelling agents were employed, although the degree of structural ordering appeared to improve for phenylene-bridged PMOs in the sequence of decreased number of methyl groups on the benzene ring." @default.
- W2321548556 created "2016-06-24" @default.
- W2321548556 creator A5026001128 @default.
- W2321548556 creator A5027331340 @default.
- W2321548556 creator A5060161804 @default.
- W2321548556 creator A5071116266 @default.
- W2321548556 date "2012-06-04" @default.
- W2321548556 modified "2023-10-16" @default.
- W2321548556 title "Face-Centered-Cubic Large-Pore Periodic Mesoporous Organosilicas with Unsaturated and Aromatic Bridging Groups" @default.
- W2321548556 cites W1544947788 @default.
- W2321548556 cites W1960530629 @default.
- W2321548556 cites W1967311510 @default.
- W2321548556 cites W1970659985 @default.
- W2321548556 cites W1971062796 @default.
- W2321548556 cites W1972920173 @default.
- W2321548556 cites W1975493559 @default.
- W2321548556 cites W1976741620 @default.
- W2321548556 cites W1980352790 @default.
- W2321548556 cites W1980704616 @default.
- W2321548556 cites W1984911567 @default.
- W2321548556 cites W1987330726 @default.
- W2321548556 cites W1988745485 @default.
- W2321548556 cites W1989632172 @default.
- W2321548556 cites W1990302960 @default.
- W2321548556 cites W1994122578 @default.
- W2321548556 cites W1995041236 @default.
- W2321548556 cites W2004458374 @default.
- W2321548556 cites W2005242641 @default.
- W2321548556 cites W2005935607 @default.
- W2321548556 cites W2011129393 @default.
- W2321548556 cites W2011246992 @default.
- W2321548556 cites W2011343104 @default.
- W2321548556 cites W2013562749 @default.
- W2321548556 cites W2017836963 @default.
- W2321548556 cites W2018238702 @default.
- W2321548556 cites W2019049494 @default.
- W2321548556 cites W2023511700 @default.
- W2321548556 cites W2025575023 @default.
- W2321548556 cites W2025801819 @default.
- W2321548556 cites W2026446312 @default.
- W2321548556 cites W2026645986 @default.
- W2321548556 cites W2027323147 @default.
- W2321548556 cites W2032603759 @default.
- W2321548556 cites W2034041168 @default.
- W2321548556 cites W2035856926 @default.
- W2321548556 cites W2036262329 @default.
- W2321548556 cites W2036725384 @default.
- W2321548556 cites W2039241045 @default.
- W2321548556 cites W2040869162 @default.
- W2321548556 cites W2041488869 @default.
- W2321548556 cites W2042442357 @default.
- W2321548556 cites W2043295591 @default.
- W2321548556 cites W2046450308 @default.
- W2321548556 cites W2048187451 @default.
- W2321548556 cites W2053638179 @default.
- W2321548556 cites W2058268700 @default.
- W2321548556 cites W2058879146 @default.
- W2321548556 cites W2059507858 @default.
- W2321548556 cites W2060609780 @default.
- W2321548556 cites W2060829596 @default.
- W2321548556 cites W2060840945 @default.
- W2321548556 cites W2062946773 @default.
- W2321548556 cites W2063228935 @default.
- W2321548556 cites W2063656674 @default.
- W2321548556 cites W2065864560 @default.
- W2321548556 cites W2072750734 @default.
- W2321548556 cites W2074091002 @default.
- W2321548556 cites W2074592175 @default.
- W2321548556 cites W2076261733 @default.
- W2321548556 cites W2078220488 @default.
- W2321548556 cites W2081784674 @default.
- W2321548556 cites W2086164824 @default.
- W2321548556 cites W2101575607 @default.
- W2321548556 cites W2103637866 @default.
- W2321548556 cites W2109951459 @default.
- W2321548556 cites W2112272805 @default.
- W2321548556 cites W2113266947 @default.
- W2321548556 cites W2122599743 @default.
- W2321548556 cites W2132581095 @default.
- W2321548556 cites W2135988370 @default.
- W2321548556 cites W2148223416 @default.
- W2321548556 cites W2158111418 @default.
- W2321548556 cites W2312199777 @default.
- W2321548556 cites W2312425325 @default.
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- W2321548556 doi "https://doi.org/10.1021/la301329c" @default.
- W2321548556 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22607203" @default.
- W2321548556 hasPublicationYear "2012" @default.
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