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• W2321743911 abstract "Weak, intermolecular forces are difficult to observe in solution because the molecular encounters are random, short-lived, and overwhelmed by the solvent. In confined spaces such as capsules and the active sites of enzymes or receptors, the encounters are prolonged, prearranged, and isolated from the medium. We report here the application of encapsulation techniques to directly observe halogen bonding. The small volume of the capsule amplifies the concentrations of both donor and acceptor, while the shape of the space permits their proper alignment. The extended lifetime of the encapsulation complex allows the weak interaction to be observed and characterized by conventional NMR methods under conditions in which the interaction would be negligible in bulk solvent." @default.
• W2321743911 created "2016-06-24" @default.
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• W2321743911 date "2013-09-05" @default.
• W2321743911 modified "2023-10-18" @default.
• W2321743911 title "Amplified Halogen Bonding in a Small Space" @default.
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• W2321743911 doi "https://doi.org/10.1021/ja407815t" @default.
• W2321743911 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24000791" @default.
• W2321743911 hasPublicationYear "2013" @default.
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