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- W2321754791 abstract "Abstract This manuscript describes the development of Pd- and Ni-catalyzed arylations of unactivated arene C–H bonds using C–O electrophiles. A method for Pd-catalyzed intramolecular C–H arylation is accomplished using inexpensive and readily available tosylates and mesylates as electrophiles. This transformation is efficient for the synthesis of various heterocyclic motifs including furans, carbazoles, indoles, and lactams. Additionally, a protocol for a one-pot sequential tosylation/arylation of phenol derivatives is presented. The use of earth-abundant and inexpensive Ni catalysts for an intramolecular C–H arylation using aryl pivalates as electrophiles is described. Preliminary mechanistic studies for both the Pd- and Ni-catalyzed arylations are discussed." @default.
- W2321754791 created "2016-06-24" @default.
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- W2321754791 date "2014-03-20" @default.
- W2321754791 modified "2023-10-15" @default.
- W2321754791 title "Pd- and Ni-catalyzed C–H arylations using C–O electrophiles" @default.
- W2321754791 cites W2031385880 @default.
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- W2321754791 doi "https://doi.org/10.1515/pac-2014-5033" @default.
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