FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321784439> ?p ?o ?g. }

• W2321784439 endingPage "544" @default.
• W2321784439 startingPage "527" @default.
• W2321784439 abstract "Two series of new, photoluminescent star-shaped discotic liquid crystals, recently termed as hekates, derived from tris(N-salicylideneaniline)s (TSANs), were synthesized by the facile threefold condensation of 3,4-bis(alkoxy)phenyl 4-aminobenzoates/3,4,5-tris(alkoxy) phenyl 4-aminobenzoates with 1,3,5-triformylphloroglucinol and characterized. These two series of discotics with six and nine peripheral n-alkoxy tails were especially designed and accomplished to understand the relation between mesomorphic/photophysical properties and molecular structure. Proton NMR spectral analysis revealed their existence as an inseparable mixture of two keto-enamine tautomeric forms featuring C(3h) and C(s) rotational symmetries. A systematic study into the thermotropic liquid crystal behavior using polarizing optical microscopy, differential scanning calorimetry, and X-ray scattering confirmed the presence of columnar (Col) phase in vast majority of the TSANs prepared. The two-dimensional (2D) lattices of these fluid columnar phases were found to be characteristic of hexagonal Col (Col(h)), rectangular Col (Col(r)), or oblique Col (Col(ob)) phases depending on the number/length of the peripheral flexible chains. The stabilization of the Col(ob) phase, a less commonly found fluid columnar structure, and the first of its kind in TSAN systems, implies very intensive intermolecular (face-to-face) interactions among the TSAN cores within the column. The photophysical properties were investigated both in solution and the columnar states by UV-vis absorption and photoluminescence; markedly, the solution state emits light in the blue region. The light-emitting ability of the Col phase is particularly significant given the possibility that, in such cores, the protons and electrons interact with each other through the H-bonding environment." @default.
• W2321784439 created "2016-06-24" @default.
• W2321784439 creator A5001394282 @default.
• W2321784439 creator A5011157018 @default.
• W2321784439 creator A5033697487 @default.
• W2321784439 creator A5058223591 @default.
• W2321784439 creator A5088827277 @default.
• W2321784439 date "2012-12-27" @default.
• W2321784439 modified "2023-09-27" @default.
• W2321784439 title "Self-Assembly of Hekates-Tris(<i>N</i>-salicylideneaniline)s into Columnar Structures: Synthesis and Characterization" @default.
• W2321784439 cites W1615675662 @default.
• W2321784439 cites W1827274357 @default.
• W2321784439 cites W1963910048 @default.
• W2321784439 cites W1966636094 @default.
• W2321784439 cites W1967250512 @default.
• W2321784439 cites W1968148714 @default.
• W2321784439 cites W1971529861 @default.
• W2321784439 cites W1977403096 @default.
• W2321784439 cites W1977720957 @default.
• W2321784439 cites W1981546475 @default.
• W2321784439 cites W1982151759 @default.
• W2321784439 cites W1983435123 @default.
• W2321784439 cites W1986115627 @default.
• W2321784439 cites W1986638595 @default.
• W2321784439 cites W1993508430 @default.
• W2321784439 cites W1995243636 @default.
• W2321784439 cites W1996558366 @default.
• W2321784439 cites W1996845550 @default.
• W2321784439 cites W1997322886 @default.
• W2321784439 cites W2004664692 @default.
• W2321784439 cites W2005796156 @default.
• W2321784439 cites W2009712659 @default.
• W2321784439 cites W2010495545 @default.
• W2321784439 cites W2010587005 @default.
• W2321784439 cites W2013945355 @default.
• W2321784439 cites W2014336773 @default.
• W2321784439 cites W2015624757 @default.
• W2321784439 cites W2015752493 @default.
• W2321784439 cites W2019383526 @default.
• W2321784439 cites W2020586725 @default.
• W2321784439 cites W2021762016 @default.
• W2321784439 cites W2024793089 @default.
• W2321784439 cites W2027737015 @default.
• W2321784439 cites W2028206308 @default.
• W2321784439 cites W2028286504 @default.
• W2321784439 cites W2031601897 @default.
• W2321784439 cites W2033292578 @default.
• W2321784439 cites W2035729433 @default.
• W2321784439 cites W2036339379 @default.
• W2321784439 cites W2037221985 @default.
• W2321784439 cites W2038026349 @default.
• W2321784439 cites W2038645023 @default.
• W2321784439 cites W2038738784 @default.
• W2321784439 cites W2044445307 @default.
• W2321784439 cites W2046704339 @default.
• W2321784439 cites W2047485457 @default.
• W2321784439 cites W2051047258 @default.
• W2321784439 cites W2052636859 @default.
• W2321784439 cites W2055499045 @default.
• W2321784439 cites W2055815818 @default.
• W2321784439 cites W2060119755 @default.
• W2321784439 cites W2060143775 @default.
• W2321784439 cites W2061384381 @default.
• W2321784439 cites W2061710637 @default.
• W2321784439 cites W2064595660 @default.
• W2321784439 cites W2065090471 @default.
• W2321784439 cites W2065706409 @default.
• W2321784439 cites W2066087445 @default.
• W2321784439 cites W2066417199 @default.
• W2321784439 cites W2070367784 @default.
• W2321784439 cites W2072936938 @default.
• W2321784439 cites W2076572659 @default.
• W2321784439 cites W2079994686 @default.
• W2321784439 cites W2081834001 @default.
• W2321784439 cites W2083691127 @default.
• W2321784439 cites W2087179202 @default.
• W2321784439 cites W2087427549 @default.
• W2321784439 cites W2087437736 @default.
• W2321784439 cites W2088944829 @default.
• W2321784439 cites W2099143020 @default.
• W2321784439 cites W2108694990 @default.
• W2321784439 cites W2108941526 @default.
• W2321784439 cites W2112269229 @default.
• W2321784439 cites W2114992412 @default.
• W2321784439 cites W2116514525 @default.
• W2321784439 cites W2120173816 @default.
• W2321784439 cites W2120526975 @default.
• W2321784439 cites W2128850923 @default.
• W2321784439 cites W2131214718 @default.
• W2321784439 cites W2134898952 @default.
• W2321784439 cites W2138604907 @default.
• W2321784439 cites W2141517543 @default.
• W2321784439 cites W2149765511 @default.
• W2321784439 cites W2151007212 @default.
• W2321784439 cites W2153171549 @default.
• W2321784439 cites W2153333011 @default.
• W2321784439 cites W2163542639 @default.
• W2321784439 cites W2170093485 @default.

• next