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- W2321813825 abstract "We report spectroscopic evidence of isomer interconversion in water cluster anions, (H2O)n(-), which occurs through the interaction with a benzene molecule. An anion complex composed of (H2O)6(-) and benzene, Bz·(H2O)6(-), is formed via the reaction of (H2O)6(-)Arm with benzene. The reaction proceeds as an Ar-mediated association process such that a rapid energy dissipation by sequential Ar evaporation efficiently suppresses the thermionic emission of e(-), H2O, or both, giving rise to the formation of Bz·(H2O)6(-). Photoelectron spectroscopy is employed to probe the electronic properties of the anionic species, which reveals that type I → type II isomer interconversion proceeds in the (H2O)6(-) moiety during the formation of Bz·(H2O)6(-). With the aid of ab initio calculations, we conclude that the interconversion is driven by preferential stabilization of the H-bond network of type II arrangement through the formation of a nonconventional O-H···π hydrogen bond between (H2O)6(-) and Bz." @default.
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- W2321813825 date "2012-11-26" @default.
- W2321813825 modified "2023-09-30" @default.
- W2321813825 title "Hydrogen-Bond Network Transformation in Water-Cluster Anions Induced by the Complex Formation with Benzene" @default.
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- W2321813825 doi "https://doi.org/10.1021/jz301599f" @default.
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