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• W2321827533 abstract "Moderate to good levels of substrate-based 1,5-syn-stereocontrol could be achieved in the boron-mediated aldol reactions of β-tert-butyl methylketones with achiral aldehydes, independent of the nature of the β-alkoxy protecting group (P = PMB or TBS). The analysis of the relative energies of the transition structures by theoretical calculations using the density functional B3LYP shows relative energies favoring the corresponding OUT-1,5-SYN transition structures, explaining the observed 1,5-syn stereoinduction." @default.
• W2321827533 created "2016-06-24" @default.
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• W2321827533 date "2010-10-08" @default.
• W2321827533 modified "2023-10-02" @default.
• W2321827533 title "Influence of β-Substituents in Aldol Reactions of Boron Enolates of β-Alkoxy Methylketones" @default.
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• W2321827533 doi "https://doi.org/10.1021/ol102303p" @default.
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