FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321829963> ?p ?o ?g. }

• W2321829963 endingPage "8387" @default.
• W2321829963 startingPage "8380" @default.
• W2321829963 abstract "Conjugated oligoelectrolytes are of emerging technological interest due to their recent function in the fabrication of optoelectronic devices, application in biosensors, and as species that facilitate transmembrane charge migration. Solubility in aqueous, or highly polar, solvents is important for many of these applications; however, there are few studies on how the self-assembly of conjugated oligoelectrolytes into multichromophore species influences linear and nonlinear optical properties. Here, we examine 1,4-bis(4'-(N,N-bis(6''-(N,N,N-trimethylammonium)hexyl)amino)-styryl)benzene tetraiodide (DSBNI) in water, a conjugated oligoelectrolyte based on the distyrylbenzene framework. We find that DSBNI aggregation leads to increased fluorescence lifetimes, coupled with hypsochromic shifts, and larger two-photon absorption cross sections. Liquid atomic force microscopy (AFM) and cryogenic transmission electron microscopy (cryo-TEM) were used to image DSBNI aggregates and to confirm that the planar molecules stack to form nanocylinders above a critical aggregation concentration. Finally, small-angle neutron scattering (SANS) was used to quantify the aggregate dimensions in situ. Comparison of the results highlights that the hydrophilic mica surface used to image via liquid AFM and the high concentrations required for cryo-TEM facilitate the propagation of the cylinders into long fibers. SANS experiments are consistent with equivalent molecular packing geometry but lower aspect ratios. It is therefore possible to understand the evolution of optical properties as a function of concentration and aggregation and the general geometric features of the resulting supramolecular structures." @default.
• W2321829963 created "2016-06-24" @default.
• W2321829963 creator A5003453769 @default.
• W2321829963 creator A5012777480 @default.
• W2321829963 creator A5013306898 @default.
• W2321829963 creator A5019248549 @default.
• W2321829963 creator A5028903718 @default.
• W2321829963 creator A5051743081 @default.
• W2321829963 creator A5059836195 @default.
• W2321829963 date "2011-05-06" @default.
• W2321829963 modified "2023-10-04" @default.
• W2321829963 title "Self-Assembly of an Optically Active Conjugated Oligoelectrolyte" @default.
• W2321829963 cites W1611437588 @default.
• W2321829963 cites W1963740321 @default.
• W2321829963 cites W1965155305 @default.
• W2321829963 cites W1966306992 @default.
• W2321829963 cites W1968770469 @default.
• W2321829963 cites W1970526168 @default.
• W2321829963 cites W1972803989 @default.
• W2321829963 cites W1976849993 @default.
• W2321829963 cites W1978381106 @default.
• W2321829963 cites W1981971855 @default.
• W2321829963 cites W1982396629 @default.
• W2321829963 cites W1982802198 @default.
• W2321829963 cites W1984035852 @default.
• W2321829963 cites W1984649466 @default.
• W2321829963 cites W1984712094 @default.
• W2321829963 cites W1985515173 @default.
• W2321829963 cites W1986433428 @default.
• W2321829963 cites W1995661108 @default.
• W2321829963 cites W2002646476 @default.
• W2321829963 cites W2009057700 @default.
• W2321829963 cites W2011971140 @default.
• W2321829963 cites W2012611961 @default.
• W2321829963 cites W2017605486 @default.
• W2321829963 cites W2020586725 @default.
• W2321829963 cites W2022299676 @default.
• W2321829963 cites W2024027867 @default.
• W2321829963 cites W2032979334 @default.
• W2321829963 cites W2043618723 @default.
• W2321829963 cites W2052148190 @default.
• W2321829963 cites W2054271134 @default.
• W2321829963 cites W2065389789 @default.
• W2321829963 cites W2069124127 @default.
• W2321829963 cites W2070653387 @default.
• W2321829963 cites W2074311615 @default.
• W2321829963 cites W2076051065 @default.
• W2321829963 cites W2077431611 @default.
• W2321829963 cites W2077973224 @default.
• W2321829963 cites W2083122354 @default.
• W2321829963 cites W2099589655 @default.
• W2321829963 cites W2105184358 @default.
• W2321829963 cites W2111550991 @default.
• W2321829963 cites W2113504999 @default.
• W2321829963 cites W2122676372 @default.
• W2321829963 cites W2135490646 @default.
• W2321829963 cites W2139914553 @default.
• W2321829963 cites W2156472420 @default.
• W2321829963 cites W2157642531 @default.
• W2321829963 cites W2162356135 @default.
• W2321829963 cites W2170408275 @default.
• W2321829963 cites W2313719882 @default.
• W2321829963 cites W2568203515 @default.
• W2321829963 doi "https://doi.org/10.1021/ja202776b" @default.
• W2321829963 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21548560" @default.
• W2321829963 hasPublicationYear "2011" @default.
• W2321829963 type Work @default.
• W2321829963 sameAs 2321829963 @default.
• W2321829963 citedByCount "37" @default.
• W2321829963 countsByYear W23218299632012 @default.
• W2321829963 countsByYear W23218299632013 @default.
• W2321829963 countsByYear W23218299632014 @default.
• W2321829963 countsByYear W23218299632015 @default.
• W2321829963 countsByYear W23218299632016 @default.
• W2321829963 countsByYear W23218299632017 @default.
• W2321829963 countsByYear W23218299632018 @default.
• W2321829963 countsByYear W23218299632019 @default.
• W2321829963 countsByYear W23218299632020 @default.
• W2321829963 countsByYear W23218299632021 @default.
• W2321829963 countsByYear W23218299632023 @default.
• W2321829963 crossrefType "journal-article" @default.
• W2321829963 hasAuthorship W2321829963A5003453769 @default.
• W2321829963 hasAuthorship W2321829963A5012777480 @default.
• W2321829963 hasAuthorship W2321829963A5013306898 @default.
• W2321829963 hasAuthorship W2321829963A5019248549 @default.
• W2321829963 hasAuthorship W2321829963A5028903718 @default.
• W2321829963 hasAuthorship W2321829963A5051743081 @default.
• W2321829963 hasAuthorship W2321829963A5059836195 @default.
• W2321829963 hasConcept C112613896 @default.
• W2321829963 hasConcept C120665830 @default.
• W2321829963 hasConcept C121332964 @default.
• W2321829963 hasConcept C125287762 @default.
• W2321829963 hasConcept C159467904 @default.
• W2321829963 hasConcept C178790620 @default.
• W2321829963 hasConcept C185592680 @default.
• W2321829963 hasConcept C2778060476 @default.
• W2321829963 hasConcept C32909587 @default.
• W2321829963 hasConcept C521977710 @default.

• next