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- W2321834265 abstract "[4Fe–4S] clusters modeled after those in organisms having three cysteine thiolates and one carboxylate were synthesized by using the tridentate thiolato chelate. X-ray structural analysis reveals that the carboxylates coordinate to the unique irons in an η1 manner rather than η2. Redox potentials show a positive shift from that of the cluster having ethanethiolate and the tridentate thiolato chelate. These properties conform to the arrangement of the [4Fe–4S] clusters in the electron transfer systems included in Rc dark operative protochlorophyllide oxidoreductase (DPOR) and formaldehyde oxidoreductase (FOR) with Pf ferredoxin." @default.
- W2321834265 created "2016-06-24" @default.
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- W2321834265 date "2013-10-08" @default.
- W2321834265 modified "2023-09-27" @default.
- W2321834265 title "[3:1] Site-Differentiated [4Fe–4S] Clusters Having One Carboxylate and Three Thiolates" @default.
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- W2321834265 doi "https://doi.org/10.1021/ic4017596" @default.
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