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- W2321836341 abstract "The methylenedioxy-aporphine whose structure had been assigned to anonaine has been synthesized from the amide resulting from the condensation of β-3,4-methylenedioxy-phenylethylamine and o-nitrophenylacetyl chloride. The amide was cyclized to the corresponding dihydroisoquinoline, the hydriodide of which was reduced and the product transformed to dl-anonaine by the Pschorr ring closure reaction. The synthetic base on methylation was converted to dl-roemerine methiodide. A comparison of the properties of the derivatives obtained from anonaine and from roemerine, the structure of which is known, supplies strong evidence in favor of the validity of the structure assigned to anonaine." @default.
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- W2321836341 date "1950-01-01" @default.
- W2321836341 modified "2023-09-30" @default.
- W2321836341 title "THE SYNTHESIS OF <i>dl</i>-ANONAINE" @default.
- W2321836341 doi "https://doi.org/10.1139/cjr50b-004" @default.
- W2321836341 hasPublicationYear "1950" @default.
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