FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321838085> ?p ?o ?g. }

• W2321838085 endingPage "6750" @default.
• W2321838085 startingPage "6740" @default.
• W2321838085 abstract "Crystal structures of chiral and racemic proteogenic amino acids are compared, over a database of 40 crystal structures and 20 chiral-racemic pairs. Wallach’s rule does not apply. Solubility data show that the racemates tend to be slightly more stable than their chiral counterparts. Lattice energies are calculated by semiempirical PIXEL methods and by several ab initio methods, which also yield molecular energies. Results, especially molecular energies, are sensitive to small structural differences and therefore depend on the crystal structure accuracy. Surface effects in crystals of zwitterionic molecules require special attention. Energy differences between chiral and racemic crystals are typically around 10 kJ mol–1, roughly the limit of our calculations. These suggest, however, that crystal stability tends to increase with decreasing crystal density, a result possibly related to the strong directionality of hydrogen bonds. The analysis of interaction energies between molecules related by specific symmetry operations shows that stabilization in homochiral crystal structures comes mainly from formation of screw-symmetric ribbons, whereas racemic crystal structures preferentially exhibit strongly stabilizing centrosymmetric dimers." @default.
• W2321838085 created "2016-06-24" @default.
• W2321838085 creator A5027624270 @default.
• W2321838085 creator A5082917032 @default.
• W2321838085 date "2012-03-15" @default.
• W2321838085 modified "2023-09-27" @default.
• W2321838085 title "Proteogenic Amino Acids: Chiral and Racemic Crystal Packings and Stabilities" @default.
• W2321838085 cites W1553081744 @default.
• W2321838085 cites W1968068945 @default.
• W2321838085 cites W1973860060 @default.
• W2321838085 cites W1979368277 @default.
• W2321838085 cites W1983235173 @default.
• W2321838085 cites W1999788049 @default.
• W2321838085 cites W2004395113 @default.
• W2321838085 cites W2010346154 @default.
• W2321838085 cites W2030038580 @default.
• W2321838085 cites W2032842297 @default.
• W2321838085 cites W2033260470 @default.
• W2321838085 cites W2034219665 @default.
• W2321838085 cites W2039300758 @default.
• W2321838085 cites W2044591029 @default.
• W2321838085 cites W2048372602 @default.
• W2321838085 cites W2067776340 @default.
• W2321838085 cites W2075533616 @default.
• W2321838085 cites W2075689727 @default.
• W2321838085 cites W2094000971 @default.
• W2321838085 cites W2097403513 @default.
• W2321838085 cites W2104467906 @default.
• W2321838085 cites W2114088212 @default.
• W2321838085 cites W2134161849 @default.
• W2321838085 cites W2149195123 @default.
• W2321838085 cites W2170012858 @default.
• W2321838085 cites W2170560995 @default.
• W2321838085 cites W2320120007 @default.
• W2321838085 cites W2324384987 @default.
• W2321838085 cites W2951568126 @default.
• W2321838085 doi "https://doi.org/10.1021/jp212094d" @default.
• W2321838085 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22360776" @default.
• W2321838085 hasPublicationYear "2012" @default.
• W2321838085 type Work @default.
• W2321838085 sameAs 2321838085 @default.
• W2321838085 citedByCount "62" @default.
• W2321838085 countsByYear W23218380852012 @default.
• W2321838085 countsByYear W23218380852013 @default.
• W2321838085 countsByYear W23218380852014 @default.
• W2321838085 countsByYear W23218380852015 @default.
• W2321838085 countsByYear W23218380852016 @default.
• W2321838085 countsByYear W23218380852017 @default.
• W2321838085 countsByYear W23218380852018 @default.
• W2321838085 countsByYear W23218380852019 @default.
• W2321838085 countsByYear W23218380852020 @default.
• W2321838085 countsByYear W23218380852021 @default.
• W2321838085 countsByYear W23218380852022 @default.
• W2321838085 countsByYear W23218380852023 @default.
• W2321838085 crossrefType "journal-article" @default.
• W2321838085 hasAuthorship W2321838085A5027624270 @default.
• W2321838085 hasAuthorship W2321838085A5082917032 @default.
• W2321838085 hasConcept C112887158 @default.
• W2321838085 hasConcept C115624301 @default.
• W2321838085 hasConcept C131468747 @default.
• W2321838085 hasConcept C147597530 @default.
• W2321838085 hasConcept C152365726 @default.
• W2321838085 hasConcept C178790620 @default.
• W2321838085 hasConcept C183971685 @default.
• W2321838085 hasConcept C185592680 @default.
• W2321838085 hasConcept C199360897 @default.
• W2321838085 hasConcept C2781285689 @default.
• W2321838085 hasConcept C2781442258 @default.
• W2321838085 hasConcept C32909587 @default.
• W2321838085 hasConcept C41008148 @default.
• W2321838085 hasConcept C486523 @default.
• W2321838085 hasConcept C71240020 @default.
• W2321838085 hasConcept C8010536 @default.
• W2321838085 hasConcept C84947059 @default.
• W2321838085 hasConceptScore W2321838085C112887158 @default.
• W2321838085 hasConceptScore W2321838085C115624301 @default.
• W2321838085 hasConceptScore W2321838085C131468747 @default.
• W2321838085 hasConceptScore W2321838085C147597530 @default.
• W2321838085 hasConceptScore W2321838085C152365726 @default.
• W2321838085 hasConceptScore W2321838085C178790620 @default.
• W2321838085 hasConceptScore W2321838085C183971685 @default.
• W2321838085 hasConceptScore W2321838085C185592680 @default.
• W2321838085 hasConceptScore W2321838085C199360897 @default.
• W2321838085 hasConceptScore W2321838085C2781285689 @default.
• W2321838085 hasConceptScore W2321838085C2781442258 @default.
• W2321838085 hasConceptScore W2321838085C32909587 @default.
• W2321838085 hasConceptScore W2321838085C41008148 @default.
• W2321838085 hasConceptScore W2321838085C486523 @default.
• W2321838085 hasConceptScore W2321838085C71240020 @default.
• W2321838085 hasConceptScore W2321838085C8010536 @default.
• W2321838085 hasConceptScore W2321838085C84947059 @default.
• W2321838085 hasIssue "23" @default.
• W2321838085 hasLocation W23218380851 @default.
• W2321838085 hasLocation W23218380852 @default.
• W2321838085 hasOpenAccess W2321838085 @default.
• W2321838085 hasPrimaryLocation W23218380851 @default.
• W2321838085 hasRelatedWork W1988977753 @default.
• W2321838085 hasRelatedWork W2039374736 @default.

• next