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- W2321845022 endingPage "11005" @default.
- W2321845022 startingPage "10999" @default.
- W2321845022 abstract "Rational catalysis design on the basis of a detailed mechanistic understanding has been used to successfully develop the first efficient general Pd-catalyzed aromatic cyanation reaction under the highly sought after practicable conditions: (i) MCN (M = Na or K) as a cyanide source; (ii) low-boiling recyclable solvents; and (iii) minimal quantities of inexpensive, nontoxic promoters. The developed catalytic reaction converts aromatic bromides to the corresponding nitriles in 88–99% isolated yield with NaCN and 0.5–1.0 mol % of a t-Bu3P-monoligated Pd catalyst in MeCN-THF within 2 h at 70 °C. The process exhibits high functional group tolerance." @default.
- W2321845022 created "2016-06-24" @default.
- W2321845022 creator A5031668331 @default.
- W2321845022 creator A5055029587 @default.
- W2321845022 date "2011-06-23" @default.
- W2321845022 modified "2023-10-06" @default.
- W2321845022 title "Rational Catalysis Design on the Basis of Mechanistic Understanding: Highly Efficient Pd-Catalyzed Cyanation of Aryl Bromides with NaCN in Recyclable Solvents" @default.
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- W2321845022 doi "https://doi.org/10.1021/ja2042035" @default.
- W2321845022 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21699208" @default.
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