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- W2321863521 abstract "The σ bond metathesis reactivity of (C5Me4H)3Sc, which has a (η5-C5Me4H)2Sc(η1-C5Me4H) structure in the solid state, has been investigated and compared with that of a conventional (C5Me4H)− metallocene complex, (C5Me4H)2Sc(η3-C3H5), 1. Complex 1 reacts with PhEEPh (E = S, Se, Te) in toluene to form the σ bond metathesis products (C3H5)EPh and [(C5Me4H)2Sc(SPh)]2, (C5Me4H)2Sc(SePh), and (C5Me4H)2Sc(TePh), respectively. Analogous reactions in toluene/THF generate the THF solvates (C5Me4H)2Sc(EPh)(THF). The monometallic sulfur derivative (C5Me4H)2Sc(Spy-κ2-S,N) forms from the reaction of 1 with 2,2′-dipyridyl disulfide, pySSpy. (C5Me4H)3Sc reacts similarly, showing that the (η1-C5Me4H)− solid-state structure yields Sc–C bond reactivity in solution." @default.
- W2321863521 created "2016-06-24" @default.
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- W2321863521 date "2011-05-09" @default.
- W2321863521 modified "2023-09-25" @default.
- W2321863521 title "σ Bond Metathesis Reactivity of Allyl Scandium Metallocenes with Diphenyldichalcogenides, PhEEPh (E = S, Se, Te)" @default.
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- W2321863521 doi "https://doi.org/10.1021/om2001876" @default.
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