FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321865480> ?p ?o ?g. }

• W2321865480 endingPage "9806" @default.
• W2321865480 startingPage "9798" @default.
• W2321865480 abstract "The synthesis of the new phosphinodi(benzylsilane) compound PhP{(o-C6H4CH2)SiMe2H}2 (1) is achieved in a one-pot reaction from the corresponding phenylbis(o-tolylphosphine). Compound 1 acts as a pincer-type ligand capable of adopting different coordination modes at Ru through different extents of Si–H bond activation as demonstrated by a combination of X-ray diffraction analysis, density functional theory calculations, and multinuclear NMR spectroscopy. Reaction of 1 with RuH2(H2)2(PCy3)2 (2) yields quantitatively [RuH2{[η2-(HSiMe2)-CH2-o-C6H4]2PPh}(PCy3)] (3), a complex stabilized by two rare high order ε-agostic Si–H bonds and involved in terminal hydride/η2-Si–H exchange processes. A small free energy of reaction (ΔrG298 = +16.9 kJ mol–1) was computed for dihydrogen loss from 3 with concomitant formation of the 16-electron species [RuH{[η2-(HSiMe2)-CH2-o-C6H4]PPh[CH2-o-C6H4SiMe2]}(PCy3)] (4). Complex 4 features an unprecedented 29Si NMR decoalescence process. The dehydrogenation process is fully reversible under standard conditions (1 bar, 298 K)." @default.
• W2321865480 created "2016-06-24" @default.
• W2321865480 creator A5006660837 @default.
• W2321865480 creator A5008612886 @default.
• W2321865480 creator A5020636360 @default.
• W2321865480 creator A5041959270 @default.
• W2321865480 creator A5054046860 @default.
• W2321865480 creator A5073788161 @default.
• W2321865480 date "2013-08-13" @default.
• W2321865480 modified "2023-10-17" @default.
• W2321865480 title "Phosphinodi(benzylsilane) PhP{(<i>o</i>-C₆H₄CH₂)SiMe₂H}₂: A Versatile “PSi₂H_<i>x</i>” Pincer-Type Ligand at Ruthenium" @default.
• W2321865480 cites W1964837435 @default.
• W2321865480 cites W1967004349 @default.
• W2321865480 cites W1973271633 @default.
• W2321865480 cites W1974980204 @default.
• W2321865480 cites W1980600557 @default.
• W2321865480 cites W1980696050 @default.
• W2321865480 cites W1997606477 @default.
• W2321865480 cites W2001641205 @default.
• W2321865480 cites W2003998471 @default.
• W2321865480 cites W2004027588 @default.
• W2321865480 cites W2006261739 @default.
• W2321865480 cites W2015723183 @default.
• W2321865480 cites W2017735459 @default.
• W2321865480 cites W2022460730 @default.
• W2321865480 cites W2022575680 @default.
• W2321865480 cites W2025066146 @default.
• W2321865480 cites W2025469282 @default.
• W2321865480 cites W2027341326 @default.
• W2321865480 cites W2030006051 @default.
• W2321865480 cites W2039490066 @default.
• W2321865480 cites W2042108185 @default.
• W2321865480 cites W2043327592 @default.
• W2321865480 cites W2046912592 @default.
• W2321865480 cites W2049079467 @default.
• W2321865480 cites W2051372059 @default.
• W2321865480 cites W2059233218 @default.
• W2321865480 cites W2059530602 @default.
• W2321865480 cites W2060056075 @default.
• W2321865480 cites W2062773259 @default.
• W2321865480 cites W2067721395 @default.
• W2321865480 cites W2074825371 @default.
• W2321865480 cites W2075691057 @default.
• W2321865480 cites W2076269363 @default.
• W2321865480 cites W2076990588 @default.
• W2321865480 cites W2078089048 @default.
• W2321865480 cites W2079223455 @default.
• W2321865480 cites W2079335545 @default.
• W2321865480 cites W2079941105 @default.
• W2321865480 cites W2082712943 @default.
• W2321865480 cites W2083038626 @default.
• W2321865480 cites W2084080623 @default.
• W2321865480 cites W2084358829 @default.
• W2321865480 cites W2084713361 @default.
• W2321865480 cites W2088052869 @default.
• W2321865480 cites W2091885653 @default.
• W2321865480 cites W2094538462 @default.
• W2321865480 cites W2094642658 @default.
• W2321865480 cites W2097923034 @default.
• W2321865480 cites W2099634855 @default.
• W2321865480 cites W2104586900 @default.
• W2321865480 cites W2105094155 @default.
• W2321865480 cites W2110323804 @default.
• W2321865480 cites W2115411735 @default.
• W2321865480 cites W2115464291 @default.
• W2321865480 cites W2125017611 @default.
• W2321865480 cites W2133320381 @default.
• W2321865480 cites W2143981217 @default.
• W2321865480 cites W2150897794 @default.
• W2321865480 cites W2152630496 @default.
• W2321865480 cites W2153954387 @default.
• W2321865480 cites W2316125765 @default.
• W2321865480 cites W2323903979 @default.
• W2321865480 cites W2324893634 @default.
• W2321865480 cites W2331496604 @default.
• W2321865480 cites W2335116514 @default.
• W2321865480 cites W2414114006 @default.
• W2321865480 cites W2952814102 @default.
• W2321865480 doi "https://doi.org/10.1021/ic400703r" @default.
• W2321865480 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23941141" @default.
• W2321865480 hasPublicationYear "2013" @default.
• W2321865480 type Work @default.
• W2321865480 sameAs 2321865480 @default.
• W2321865480 citedByCount "24" @default.
• W2321865480 countsByYear W23218654802013 @default.
• W2321865480 countsByYear W23218654802014 @default.
• W2321865480 countsByYear W23218654802015 @default.
• W2321865480 countsByYear W23218654802016 @default.
• W2321865480 countsByYear W23218654802017 @default.
• W2321865480 countsByYear W23218654802018 @default.
• W2321865480 countsByYear W23218654802019 @default.
• W2321865480 countsByYear W23218654802021 @default.
• W2321865480 countsByYear W23218654802022 @default.
• W2321865480 crossrefType "journal-article" @default.
• W2321865480 hasAuthorship W2321865480A5006660837 @default.
• W2321865480 hasAuthorship W2321865480A5008612886 @default.
• W2321865480 hasAuthorship W2321865480A5020636360 @default.
• W2321865480 hasAuthorship W2321865480A5041959270 @default.

• next