Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321869432> ?p ?o ?g. }
Showing items 1 to 59 of
59
with 100 items per page.
- W2321869432 endingPage "102" @default.
- W2321869432 startingPage "93" @default.
- W2321869432 abstract "The chloro-bridged complexes [Cp*MCl2]2 (Cp*=C5Me5, M=Ir, Rh), [(p-cymene)RuCl2]2, [(C6Me6)RuCl2]2 and [(PEt3)PdCl2]2 react with SAMP by cleavage of the chloro bridges to give the corresponding monomeric η1-SAMP complexes. The X-ray structural determinations of [Cp*RhCl2NH2N(CH(CH2OCH3)(CH2)3)] and [(C6Me6)RuCl2NH2N(CH(CH2OCH3)(CH2)3)] show coordination of the amino group in these complexes. From the chloro-bridged complexes, SAMP and sodium α-ketocarboxylates Schiff-base N,O-chelate complexes were obtained. The structure of the [Cp*(Cl)IrO2CC(CH3)NN(CH(CH2OCH3)(CH2)3)] complex with coordination of the carboxylate-O and the imine-N atom was determined by X-ray diffraction. Die chloroverbrückten Komplexe [Cp*MCl2]2 (Cp*=C5Me5, M=Ir, Rh), [(p-Cymol)RuCl2]2, [C6Me6RuCl2]2 und [(PEt3)PdCl2]2 reagieren mit SAMP unter Spaltung der Chlorbrücken zu den entsprechenden monomeren η1-SAMP Komplexen. Die Röntgenstrukturanalysen von [Cp*RhCl2NH2N(CH(CH2OCH3)(CH2)3)] und [(C6Me6)RuCl2NH2N(CH(CH2OCH3)(CH2)3)] zeigen, daß die Koordination über die NH2-Gruppe erfolgt. Aus den chloroverbrückten Komplexen und SAMP entstehen in Gegenwart von Natrium-α-ketocarboxylaten Schiff-Base-N,O-Chelatkomplexe. Die Koordination des Carboxylat-O- und Imin-N-Atoms in [Cp*(Cl)IrO2CC(CH3)NN(CH(CH2OCH3)(CH2)3)] wurde durch röntgenographische Bestimmung der Molekülstruktur bewiesen." @default.
- W2321869432 created "2016-06-24" @default.
- W2321869432 creator A5029991550 @default.
- W2321869432 date "1999-03-27" @default.
- W2321869432 modified "2023-10-16" @default.
- W2321869432 title "Halbsandwich-Komplexe von (S)-1-Amino-2-(methoxymethyl)pyrrolidin (SAMP)" @default.
- W2321869432 doi "https://doi.org/10.1016/s0022-328x(98)01030-4" @default.
- W2321869432 hasPublicationYear "1999" @default.
- W2321869432 type Work @default.
- W2321869432 sameAs 2321869432 @default.
- W2321869432 citedByCount "6" @default.
- W2321869432 countsByYear W23218694322013 @default.
- W2321869432 crossrefType "journal-article" @default.
- W2321869432 hasAuthorship W2321869432A5029991550 @default.
- W2321869432 hasConcept C155647269 @default.
- W2321869432 hasConcept C161790260 @default.
- W2321869432 hasConcept C166940927 @default.
- W2321869432 hasConcept C178790620 @default.
- W2321869432 hasConcept C185592680 @default.
- W2321869432 hasConcept C2776428424 @default.
- W2321869432 hasConcept C2776573223 @default.
- W2321869432 hasConcept C2778074193 @default.
- W2321869432 hasConcept C521977710 @default.
- W2321869432 hasConcept C55493867 @default.
- W2321869432 hasConcept C71240020 @default.
- W2321869432 hasConcept C8010536 @default.
- W2321869432 hasConceptScore W2321869432C155647269 @default.
- W2321869432 hasConceptScore W2321869432C161790260 @default.
- W2321869432 hasConceptScore W2321869432C166940927 @default.
- W2321869432 hasConceptScore W2321869432C178790620 @default.
- W2321869432 hasConceptScore W2321869432C185592680 @default.
- W2321869432 hasConceptScore W2321869432C2776428424 @default.
- W2321869432 hasConceptScore W2321869432C2776573223 @default.
- W2321869432 hasConceptScore W2321869432C2778074193 @default.
- W2321869432 hasConceptScore W2321869432C521977710 @default.
- W2321869432 hasConceptScore W2321869432C55493867 @default.
- W2321869432 hasConceptScore W2321869432C71240020 @default.
- W2321869432 hasConceptScore W2321869432C8010536 @default.
- W2321869432 hasIssue "1" @default.
- W2321869432 hasLocation W23218694321 @default.
- W2321869432 hasOpenAccess W2321869432 @default.
- W2321869432 hasPrimaryLocation W23218694321 @default.
- W2321869432 hasRelatedWork W2002062128 @default.
- W2321869432 hasRelatedWork W2061649101 @default.
- W2321869432 hasRelatedWork W2588021590 @default.
- W2321869432 hasRelatedWork W2952062825 @default.
- W2321869432 hasRelatedWork W3132477402 @default.
- W2321869432 hasRelatedWork W321768807 @default.
- W2321869432 hasRelatedWork W4210708140 @default.
- W2321869432 hasRelatedWork W4327546753 @default.
- W2321869432 hasRelatedWork W4327546884 @default.
- W2321869432 hasRelatedWork W915291948 @default.
- W2321869432 hasVolume "577" @default.
- W2321869432 isParatext "false" @default.
- W2321869432 isRetracted "false" @default.
- W2321869432 magId "2321869432" @default.
- W2321869432 workType "article" @default.