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- W2321869872 abstract "Fiber-loop cavity ring-down spectroscopy (CRDS) is a highly sensitive spectroscopic absorption technique which has shown considerable promise for the analysis of small-volume liquid samples. We have developed a new light coupling method for fiber-loop CRDS, which overcomes two disadvantages of the technique: low efficiency light coupling into the cavity and high loss per pass. The coupler is based on a 45° reflective notch polished between 10 and 30 μm into the core of a large-core-diameter (365 μm) optical fiber, and allows for nearly 100% light coupling into the cavity, with a low loss per pass (<4%). The coupler has the additional advantage that the input and output light is spatially separated on opposite sides of the fiber. The detection sensitivity of a fiber-loop CRD spectrometer employing the new coupling method is established from ring-down measurements on aqueous rhodamine 6G (Rh6G) at 532 nm. The results are compared with data obtained using the same light source and detector, but a conventional bend-coupled small-core-diameter (50 μm) optical fiber loop. With our new coupler, a detection limit of 0.11 cm–1 is found, which corresponds to detection of 0.93 μM Rh6G in a volume of only 19 nL. This is an improvement of over an order of magnitude on our bend-coupled small-core optical fiber results, in which a detection limit of 5.3 cm–1 was found, corresponding to a detection of 43 μM Rh6G in a volume of 20 pL." @default.
- W2321869872 created "2016-06-24" @default.
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- W2321869872 date "2011-10-28" @default.
- W2321869872 modified "2023-09-26" @default.
- W2321869872 title "Top Notch Design for Fiber-Loop Cavity Ring-Down Spectroscopy" @default.
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- W2321869872 doi "https://doi.org/10.1021/ac201775f" @default.
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