Matches in SemOpenAlex for { <https://semopenalex.org/work/W2321876220> ?p ?o ?g. }
- W2321876220 endingPage "18706" @default.
- W2321876220 startingPage "18696" @default.
- W2321876220 abstract "We have performed TEM, Raman microspectroscopy, and NanoSIMS characterization of borosilicate glass samples altered for nearly 26 years at 90 °C in a confined granitic medium in order to better understand the rate-limiting mechanisms under conditions representative of a deep geological repository for vitrified radioactive waste. For the first time, we show a thick interphase that behaves like a diffusion barrier between the pristine glass and the other alteration products (porous gel and crystalline phases). Our findings indicate that the glass undergoes two distinct irreversible reactions: (i) hydration of the pristine glass controlled by water diffusion with a diffusion coefficient of 2 × 10–21 m2/s and (ii) transformation of the hydrated glass into a macroporous gel with major structural changes. Both materials are nonstoichiometric and metastable. A final reversible reaction leads to the formation of crystalline phases that consume elements forming the gel layer and the hydrated glass. All these react..." @default.
- W2321876220 created "2016-06-24" @default.
- W2321876220 creator A5000666154 @default.
- W2321876220 creator A5009465699 @default.
- W2321876220 creator A5016598150 @default.
- W2321876220 creator A5023365463 @default.
- W2321876220 creator A5026718442 @default.
- W2321876220 creator A5029187631 @default.
- W2321876220 creator A5088908271 @default.
- W2321876220 date "2011-08-31" @default.
- W2321876220 modified "2023-10-06" @default.
- W2321876220 title "Nuclear Glass Durability: New Insight into Alteration Layer Properties" @default.
- W2321876220 cites W1966342098 @default.
- W2321876220 cites W1968392515 @default.
- W2321876220 cites W1971358057 @default.
- W2321876220 cites W1971938807 @default.
- W2321876220 cites W1972688207 @default.
- W2321876220 cites W1974806774 @default.
- W2321876220 cites W1979999682 @default.
- W2321876220 cites W1980728284 @default.
- W2321876220 cites W1985405994 @default.
- W2321876220 cites W1988382752 @default.
- W2321876220 cites W1989107616 @default.
- W2321876220 cites W1995830122 @default.
- W2321876220 cites W1999100986 @default.
- W2321876220 cites W2001757038 @default.
- W2321876220 cites W2006009278 @default.
- W2321876220 cites W2008758996 @default.
- W2321876220 cites W2010379881 @default.
- W2321876220 cites W2012949159 @default.
- W2321876220 cites W2015078825 @default.
- W2321876220 cites W2017755127 @default.
- W2321876220 cites W2023018574 @default.
- W2321876220 cites W2027157747 @default.
- W2321876220 cites W2028690288 @default.
- W2321876220 cites W2038718441 @default.
- W2321876220 cites W2038989974 @default.
- W2321876220 cites W2039929173 @default.
- W2321876220 cites W2041036029 @default.
- W2321876220 cites W2041148609 @default.
- W2321876220 cites W2043022339 @default.
- W2321876220 cites W2044505503 @default.
- W2321876220 cites W2046455283 @default.
- W2321876220 cites W2047729183 @default.
- W2321876220 cites W2047773356 @default.
- W2321876220 cites W2051111809 @default.
- W2321876220 cites W2051215787 @default.
- W2321876220 cites W2051436808 @default.
- W2321876220 cites W2052193670 @default.
- W2321876220 cites W2055813487 @default.
- W2321876220 cites W2061097344 @default.
- W2321876220 cites W2062300453 @default.
- W2321876220 cites W2063879550 @default.
- W2321876220 cites W2065188346 @default.
- W2321876220 cites W2068732727 @default.
- W2321876220 cites W2068861941 @default.
- W2321876220 cites W2069414620 @default.
- W2321876220 cites W2071646454 @default.
- W2321876220 cites W2072522002 @default.
- W2321876220 cites W2073806047 @default.
- W2321876220 cites W2074509464 @default.
- W2321876220 cites W2083718203 @default.
- W2321876220 cites W2085461940 @default.
- W2321876220 cites W2085797930 @default.
- W2321876220 cites W2087144840 @default.
- W2321876220 cites W2087309223 @default.
- W2321876220 cites W2087853358 @default.
- W2321876220 cites W2094696834 @default.
- W2321876220 cites W2119618049 @default.
- W2321876220 cites W2120524165 @default.
- W2321876220 cites W2125566244 @default.
- W2321876220 cites W2137683389 @default.
- W2321876220 cites W2149222984 @default.
- W2321876220 cites W2151422015 @default.
- W2321876220 cites W2154271231 @default.
- W2321876220 cites W2162423222 @default.
- W2321876220 cites W2170201259 @default.
- W2321876220 cites W2171212909 @default.
- W2321876220 cites W2283421832 @default.
- W2321876220 cites W2315238821 @default.
- W2321876220 cites W2320245308 @default.
- W2321876220 cites W2331599080 @default.
- W2321876220 cites W4242137127 @default.
- W2321876220 doi "https://doi.org/10.1021/jp205477q" @default.
- W2321876220 hasPublicationYear "2011" @default.
- W2321876220 type Work @default.
- W2321876220 sameAs 2321876220 @default.
- W2321876220 citedByCount "114" @default.
- W2321876220 countsByYear W23218762202012 @default.
- W2321876220 countsByYear W23218762202013 @default.
- W2321876220 countsByYear W23218762202014 @default.
- W2321876220 countsByYear W23218762202015 @default.
- W2321876220 countsByYear W23218762202016 @default.
- W2321876220 countsByYear W23218762202017 @default.
- W2321876220 countsByYear W23218762202018 @default.
- W2321876220 countsByYear W23218762202019 @default.
- W2321876220 countsByYear W23218762202020 @default.
- W2321876220 countsByYear W23218762202021 @default.