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- W2321880097 abstract "Rate coefficients from laboratory measurements at 300 K are reported for reactions of cyanoacetylene, HC3N, with 18 ions of interstellar significance. Reactions between HC3N and ions of the type YH+ were found to be exclusively proton transfer except in the case where Y = NH3 where no reaction occurred. These observations limit the proton affinity of HC3N to the range between 824 and 866 kJ/mol. Reactions between HC3N and ions with non-transferable protons, Y+, were exclusively charge transfer with rate coefficients in most cases exceeding the predictions of the simple polarization and orientated dipole models. A further consequence of the high proton affinity of HC3N is that HC5N will not be formed from HC3N via the reaction|$text{C}_{2}text{H}_{3}^{+}+text{HC}_{3}text{N}rightarrow text{H}_{2}text{C}_{5}text{N}^{+}+text{H}_{2}$|." @default.
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- W2321880097 date "1979-07-01" @default.
- W2321880097 modified "2023-09-28" @default.
- W2321880097 title "Laboratory investigation of ion-molecule reactions of HC3N in dense interstellar clouds" @default.
- W2321880097 doi "https://doi.org/10.1093/mnras/187.3.441" @default.
- W2321880097 hasPublicationYear "1979" @default.
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