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• W2321885497 startingPage "10762" @default.
• W2321885497 abstract "The first total synthesis of (S)-6-(2,9-dihydroxynonyl)-4-hydroxy-3-methyl-2H-pyran-2-one, 4-hydroxy-3-methyl-6-((2S,4R)-2,4,11-trihydroxyundecyl)-2H-pyran-2-one, and its unnatural 2R,4R-isomer starting from commercially available 1,8-octanediol is described. The synthesis led to the revision of the proposed structural assignment of the natural product as (R)-6-(2,9-dihydroxynonyl)-4-hydroxy-3-methyl-2H-pyran-2-one. The key steps include chiral auxiliary mediated asymmetric acetate aldol reaction, dianion addition, and base mediated cyclization to form an α-pyrone ring." @default.
• W2321885497 created "2016-06-24" @default.
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• W2321885497 date "2014-11-04" @default.
• W2321885497 modified "2023-09-23" @default.
• W2321885497 title "Synthesis and Determination of Absolute Configuration of α-Pyrones Isolated from <i>Penicillium corylophilum</i>" @default.
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• W2321885497 doi "https://doi.org/10.1021/jo5015382" @default.
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• W2321885497 hasPublicationYear "2014" @default.
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