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- W2321889473 endingPage "40" @default.
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- W2321889473 abstract "This review summarizes the electronic coupling studies in mixed-valence or donor–acceptor -type complexes containing one or two cyclometalated ruthenium redox sites. Basic electron transfer theories and analysis methods for mixed-valence compounds are introduced, followed by the discussion on the electronic coupling studies of symmetric diruthenium complexes. The effects of the RuC bond and the position of the RuC bond on the degree of electronic coupling are highlighted. The uses of different bridging ligands and terminal ligands can greatly modulate the degree of coupling. Complexes with a [NCN-NCN]-type bridging ligand show much stronger electronic coupling with respect to those with a [NNN-NNN]- or [NNC-NNC]-type bridging ligand. In addition, two types of asymmetric complexes are discussed, including redox-asymmetric diruthenium complexes and monoruthenium complexes containing an additional redox-active site. The two-state Hush theory is used to derive the electronic coupling parameters of these complexes. DFT and TDDFT calculations are used to rationalize the spin density distribution and charge transfer transitions of selected odd-electron complexes. Future aspects of the studies on redox-active cyclometalated ruthenium complexes are briefly discussed." @default.
- W2321889473 created "2016-06-24" @default.
- W2321889473 creator A5002045094 @default.
- W2321889473 creator A5013337744 @default.
- W2321889473 creator A5015997947 @default.
- W2321889473 creator A5091472912 @default.
- W2321889473 date "2016-04-01" @default.
- W2321889473 modified "2023-10-17" @default.
- W2321889473 title "Electronic coupling in cyclometalated ruthenium complexes" @default.
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